113Cd MAS and static NMR study of halogenocadmate crystals

S. Sakida, Y. Kawamoto

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

113Cd magic-angle spinning (MAS) and static NMR spectra are measured using 23 kinds of halogenocadmate crystals with known structures to determine the isotropic chemical shifts (δiso), chemical shift anisotropies (Δδ), and asymmetry parameters η and then to discuss the relationship among these NMR parameters and the halide-anion co-ordination environments around Cd2+. The δiso(MAS) values of halide-anion co-ordination polyhedra of Cd2+ largely change with the kind of halide-anion and the halide-anion co-ordination number. The |Δδ| and η in halogenocadmate crystals is largely dependent on the structure type of crystal, but is independent of the halide-anion co-ordination number of Cd2+.

Original languageEnglish
Pages (from-to)151-161
Number of pages11
JournalJournal of Physics and Chemistry of Solids
Volume63
Issue number1
DOIs
Publication statusPublished - Jan 1 2001
Externally publishedYes

Keywords

  • A. Inorganic compounds
  • D. Nuclear magnetic resonance (NMR)

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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