113Cd MAS and Static NMR Study of Chlorocadmate Glasses

Shinichi Sakida, Hironobu Nakata, Yoji Kawamoto

Research output: Contribution to journalArticle

Abstract

113Cd magic-angle spinning (MAS) and static NMR spectra were measured of fourteen kinds of chlorocadmate glasses to reveal the chlorine coordination environments around Cd2+ in the glasses in detail. The spectra of the glasses suggest that the glass structures are mainly composed of infinite double-chains of edge-shared CdCl6 octahedra, being independent of the CdCl2 content and the kinds of chlorides except for CdCl2. 113Cd MAS and static NMR spectroscopies enabled us to reveal not only chlorine coordination number of Cd but also linkage manners between CdCl6 octahedra in the glasses.

Original languageEnglish
Pages (from-to)786-787
Number of pages2
JournalChemistry Letters
Volume32
Issue number9
DOIs
Publication statusPublished - Sep 5 2003

ASJC Scopus subject areas

  • Chemistry(all)

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