TY - JOUR
T1 - Sulfur-bonded 2-methylthiopyridine (2-MeSpy) complex of iridium(III). Crystal structure of [Cp*IrI 2-(2-MeSpy-κS)] (Cp* = η 5-C 5Me 5)
AU - Sekioka, Yusuke
AU - Suzuki, Takayoshi
PY - 2006/12/22
Y1 - 2006/12/22
N2 - A reaction of [Cp*Ir(2-Spy)(N 3)] (Cp* = pentamethylcyclopentadienyl; 2-Spy = 2-pyridinethiolate) with two equivalents of methyl iodide afforded the diiodo complex bearing 2-MeSpy, [Cp*IrI 2(2-MeSpy)] (3). From X-ray crystallography and IR spectroscopy, the S atom of 2-MeSpy is coordinated to the metal ion in the solid state. In CD 2Cl 2, complex 3 exhibited a dissociation equilibrium of 2-MeSpy similar to the corresponding thioanisole complex of [Cp*IrI 2(MeSPh)].
AB - A reaction of [Cp*Ir(2-Spy)(N 3)] (Cp* = pentamethylcyclopentadienyl; 2-Spy = 2-pyridinethiolate) with two equivalents of methyl iodide afforded the diiodo complex bearing 2-MeSpy, [Cp*IrI 2(2-MeSpy)] (3). From X-ray crystallography and IR spectroscopy, the S atom of 2-MeSpy is coordinated to the metal ion in the solid state. In CD 2Cl 2, complex 3 exhibited a dissociation equilibrium of 2-MeSpy similar to the corresponding thioanisole complex of [Cp*IrI 2(MeSPh)].
UR - http://www.scopus.com/inward/record.url?scp=33845598011&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33845598011&partnerID=8YFLogxK
U2 - 10.1246/bcsj.79.1897
DO - 10.1246/bcsj.79.1897
M3 - Article
AN - SCOPUS:33845598011
SN - 0009-2673
VL - 79
SP - 1897
EP - 1899
JO - Bulletin of the Chemical Society of Japan
JF - Bulletin of the Chemical Society of Japan
IS - 12
ER -