TY - JOUR
T1 - Structure-morphology-mechanical properties relationship of some polypropylene/lignocellulosic composites
AU - Pǎrpǎriţǎ, Elena
AU - Darie, Raluca Nicoleta
AU - Popescu, Carmen Mihaela
AU - Uddin, Md Azhar
AU - Vasile, Cornelia
N1 - Funding Information:
The authors are grateful for the support received by Marie Curie FP7 program, Grant PIRSES GA-2009–247550 BIOFUEL and also they thank to eng. Elena Marlică for technical assistance wth XRD experiments.
PY - 2014/4
Y1 - 2014/4
N2 - Natural lignocellulosic materials have an outstanding potential as thermoplastic reinforcement. Polypropylene composites were prepared using different types of lignocellulosic materials by melt blending of 70 wt% polypropylene (PP) and 30 wt% biomasses. The specimens werefirstly evaluated for structural and morphological properties by infrared spectroscopy, X-ray diffraction, scanning electron and polarized optical microscopy. Depending on the biomass type, there were evidenced some particular shifts of the infrared bands and also crystallinity changes. An increase in crystallinity is explained by nucleating agent role of biomass. The morphological changes are directly related to variation in mechanical and rheological properties, an increase in Young modulus, melt viscosity and storage and loss moduli being recorded.
AB - Natural lignocellulosic materials have an outstanding potential as thermoplastic reinforcement. Polypropylene composites were prepared using different types of lignocellulosic materials by melt blending of 70 wt% polypropylene (PP) and 30 wt% biomasses. The specimens werefirstly evaluated for structural and morphological properties by infrared spectroscopy, X-ray diffraction, scanning electron and polarized optical microscopy. Depending on the biomass type, there were evidenced some particular shifts of the infrared bands and also crystallinity changes. An increase in crystallinity is explained by nucleating agent role of biomass. The morphological changes are directly related to variation in mechanical and rheological properties, an increase in Young modulus, melt viscosity and storage and loss moduli being recorded.
KW - Composites
KW - Lignocellulosic materials
KW - Polypropylene
KW - Structural-morphological-mechanical-rheological properties
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U2 - 10.1016/j.matdes.2013.12.033
DO - 10.1016/j.matdes.2013.12.033
M3 - Article
AN - SCOPUS:84890820004
VL - 56
SP - 763
EP - 772
JO - International Journal of Materials in Engineering Applications
JF - International Journal of Materials in Engineering Applications
SN - 0261-3069
ER -