Structure and Reactions of Radicals Derived from Cyclopentane, Cyclopentenes, and Cyclohexenes in Low-Temperature Matrices. An ESR Study

Yoshihiro Kubozono, Makoto Okada, Makoto Aoyagi, Shuichi Yahiro, Yasuhiko Gondo

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The radical species derived from cyclopentane, cyclopentenes and cyclohexenes by 60Co γ-ray irradiation at 77 K in halocarbon matrices have been studied by ESR spectroscopy. The electronic and geometrical structures of the radical species are discussed on the basis of the experimental hyperfine coupling constants and semiempirical MO calculations. Exposure of the tetramethylsilane frozen solution containing cyclopentene to 60Co γ-rays produced specifically 3-cyclopenten-l-yl.

Original languageEnglish
Pages (from-to)993-1000
Number of pages8
JournalZeitschrift fur Naturforschung - Section A Journal of Physical Sciences
Volume46
Issue number11
DOIs
Publication statusPublished - Nov 1 1991
Externally publishedYes

Fingerprint

Cyclohexenes
Cyclopentanes
Paramagnetic resonance
Half line
rays
halocarbons
matrices
Halocarbons
Irradiation
Spectroscopy
Electronics
electronic structure
Temperature
irradiation
spectroscopy

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Mathematical Physics
  • Physics and Astronomy(all)

Cite this

Structure and Reactions of Radicals Derived from Cyclopentane, Cyclopentenes, and Cyclohexenes in Low-Temperature Matrices. An ESR Study. / Kubozono, Yoshihiro; Okada, Makoto; Aoyagi, Makoto; Yahiro, Shuichi; Gondo, Yasuhiko.

In: Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences, Vol. 46, No. 11, 01.11.1991, p. 993-1000.

Research output: Contribution to journalArticle

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