Abstract
The radical species derived from cyclopentane, cyclopentenes and cyclohexenes by 60Co γ-ray irradiation at 77 K in halocarbon matrices have been studied by ESR spectroscopy. The electronic and geometrical structures of the radical species are discussed on the basis of the experimental hyperfine coupling constants and semiempirical MO calculations. Exposure of the tetramethylsilane frozen solution containing cyclopentene to 60Co γ-rays produced specifically 3-cyclopenten-l-yl.
| Original language | English |
|---|---|
| Pages (from-to) | 993-1000 |
| Number of pages | 8 |
| Journal | Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences |
| Volume | 46 |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - Nov 1 1991 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Mathematical Physics
- Physics and Astronomy(all)
Cite this
Structure and Reactions of Radicals Derived from Cyclopentane, Cyclopentenes, and Cyclohexenes in Low-Temperature Matrices. An ESR Study. / Kubozono, Yoshihiro; Okada, Makoto; Aoyagi, Makoto; Yahiro, Shuichi; Gondo, Yasuhiko.
In: Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences, Vol. 46, No. 11, 01.11.1991, p. 993-1000.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Structure and Reactions of Radicals Derived from Cyclopentane, Cyclopentenes, and Cyclohexenes in Low-Temperature Matrices. An ESR Study
AU - Kubozono, Yoshihiro
AU - Okada, Makoto
AU - Aoyagi, Makoto
AU - Yahiro, Shuichi
AU - Gondo, Yasuhiko
PY - 1991/11/1
Y1 - 1991/11/1
N2 - The radical species derived from cyclopentane, cyclopentenes and cyclohexenes by 60Co γ-ray irradiation at 77 K in halocarbon matrices have been studied by ESR spectroscopy. The electronic and geometrical structures of the radical species are discussed on the basis of the experimental hyperfine coupling constants and semiempirical MO calculations. Exposure of the tetramethylsilane frozen solution containing cyclopentene to 60Co γ-rays produced specifically 3-cyclopenten-l-yl.
AB - The radical species derived from cyclopentane, cyclopentenes and cyclohexenes by 60Co γ-ray irradiation at 77 K in halocarbon matrices have been studied by ESR spectroscopy. The electronic and geometrical structures of the radical species are discussed on the basis of the experimental hyperfine coupling constants and semiempirical MO calculations. Exposure of the tetramethylsilane frozen solution containing cyclopentene to 60Co γ-rays produced specifically 3-cyclopenten-l-yl.
UR - http://www.scopus.com/inward/record.url?scp=84945033616&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84945033616&partnerID=8YFLogxK
U2 - 10.1515/zna-1991-1111
DO - 10.1515/zna-1991-1111
M3 - Article
AN - SCOPUS:84945033616
VL - 46
SP - 993
EP - 1000
JO - Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences
JF - Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences
SN - 0932-0784
IS - 11
ER -