Structure and Reactions of Radicals Derived from Cyclopentane, Cyclopentenes, and Cyclohexenes in Low-Temperature Matrices. An ESR Study

Yoshihiro Kubozono; Makoto Okada; Makoto Aoyagi; Shuichi Yahiro; Yasuhiko Gondo

doi:10.1515/zna-1991-1111

Structure and Reactions of Radicals Derived from Cyclopentane, Cyclopentenes, and Cyclohexenes in Low-Temperature Matrices. An ESR Study

Yoshihiro Kubozono, Makoto Okada, Makoto Aoyagi, Shuichi Yahiro, Yasuhiko Gondo

Research output: Contribution to journal › Article

1 Citation (Scopus)

Abstract

The radical species derived from cyclopentane, cyclopentenes and cyclohexenes by ⁶⁰Co γ-ray irradiation at 77 K in halocarbon matrices have been studied by ESR spectroscopy. The electronic and geometrical structures of the radical species are discussed on the basis of the experimental hyperfine coupling constants and semiempirical MO calculations. Exposure of the tetramethylsilane frozen solution containing cyclopentene to ⁶⁰Co γ-rays produced specifically 3-cyclopenten-l-yl.

Original language	English
Pages (from-to)	993-1000
Number of pages	8
Journal	Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences
Volume	46
Issue number	11
DOIs	https://doi.org/10.1515/zna-1991-1111
Publication status	Published - Nov 1 1991
Externally published	Yes

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ASJC Scopus subject areas

Mathematical Physics
Physics and Astronomy(all)
Physical and Theoretical Chemistry

Cite this

Kubozono, Y., Okada, M., Aoyagi, M., Yahiro, S., & Gondo, Y. (1991). Structure and Reactions of Radicals Derived from Cyclopentane, Cyclopentenes, and Cyclohexenes in Low-Temperature Matrices. An ESR Study. Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences, 46(11), 993-1000. https://doi.org/10.1515/zna-1991-1111

Structure and Reactions of Radicals Derived from Cyclopentane, Cyclopentenes, and Cyclohexenes in Low-Temperature Matrices. An ESR Study. / Kubozono, Yoshihiro; Okada, Makoto; Aoyagi, Makoto; Yahiro, Shuichi; Gondo, Yasuhiko.

In: Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences, Vol. 46, No. 11, 01.11.1991, p. 993-1000.

Research output: Contribution to journal › Article

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10.1515/zna-1991-1111