Abstract
The BaO-TiO2-SiO2 crystallized glass containing Ba2TiSi2O8 crystal phase was examined using X-ray diffraction (XRD) measurement and Maker fringe technique. It has been found that the crystallized glasses with a composition of close to the stoichiometric Ba2TiSi2O8 showed bulk crystallization, whereas other crystallized glasses with non-stoichiometric composition of Ba2TiSi2O8 showed surface crystallization. The parameter ΔT, the difference in temperature between the crystallization onset and the glass transition temperature, strongly affects the crystallization behaviors of the present BTS glasses. The 30BaO-20TiO2-50SiO2 transparent surface crystallized glass with strong c-oriented Ba2TiSi2O8 phase showed its second-order non-linear optical constant, d33 = 6.1 pm/V.
| Original language | English |
|---|---|
| Pages (from-to) | 2258-2262 |
| Number of pages | 5 |
| Journal | Journal of Non-Crystalline Solids |
| Volume | 353 |
| Issue number | 22-23 |
| DOIs | |
| Publication status | Published - Jul 1 2007 |
| Externally published | Yes |
Fingerprint
Keywords
- Glass ceramics
- Non-linear optics
ASJC Scopus subject areas
- Ceramics and Composites
- Electronic, Optical and Magnetic Materials
Cite this
Structure and non-linear optical properties of BaO-TiO2-SiO2 glass containing Ba2TiSi2O8 crystal. / Masai, Hirokazu; Tsuji, Shinji; Fujiwara, Takumi; Benino, Yasuhiko; Komatsu, Takayuki.
In: Journal of Non-Crystalline Solids, Vol. 353, No. 22-23, 01.07.2007, p. 2258-2262.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Structure and non-linear optical properties of BaO-TiO2-SiO2 glass containing Ba2TiSi2O8 crystal
AU - Masai, Hirokazu
AU - Tsuji, Shinji
AU - Fujiwara, Takumi
AU - Benino, Yasuhiko
AU - Komatsu, Takayuki
PY - 2007/7/1
Y1 - 2007/7/1
N2 - The BaO-TiO2-SiO2 crystallized glass containing Ba2TiSi2O8 crystal phase was examined using X-ray diffraction (XRD) measurement and Maker fringe technique. It has been found that the crystallized glasses with a composition of close to the stoichiometric Ba2TiSi2O8 showed bulk crystallization, whereas other crystallized glasses with non-stoichiometric composition of Ba2TiSi2O8 showed surface crystallization. The parameter ΔT, the difference in temperature between the crystallization onset and the glass transition temperature, strongly affects the crystallization behaviors of the present BTS glasses. The 30BaO-20TiO2-50SiO2 transparent surface crystallized glass with strong c-oriented Ba2TiSi2O8 phase showed its second-order non-linear optical constant, d33 = 6.1 pm/V.
AB - The BaO-TiO2-SiO2 crystallized glass containing Ba2TiSi2O8 crystal phase was examined using X-ray diffraction (XRD) measurement and Maker fringe technique. It has been found that the crystallized glasses with a composition of close to the stoichiometric Ba2TiSi2O8 showed bulk crystallization, whereas other crystallized glasses with non-stoichiometric composition of Ba2TiSi2O8 showed surface crystallization. The parameter ΔT, the difference in temperature between the crystallization onset and the glass transition temperature, strongly affects the crystallization behaviors of the present BTS glasses. The 30BaO-20TiO2-50SiO2 transparent surface crystallized glass with strong c-oriented Ba2TiSi2O8 phase showed its second-order non-linear optical constant, d33 = 6.1 pm/V.
KW - Glass ceramics
KW - Non-linear optics
UR - http://www.scopus.com/inward/record.url?scp=34248579193&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=34248579193&partnerID=8YFLogxK
U2 - 10.1016/j.jnoncrysol.2007.03.005
DO - 10.1016/j.jnoncrysol.2007.03.005
M3 - Article
AN - SCOPUS:34248579193
VL - 353
SP - 2258
EP - 2262
JO - Journal of Non-Crystalline Solids
JF - Journal of Non-Crystalline Solids
SN - 0022-3093
IS - 22-23
ER -