Structure and non-linear optical properties of BaO-TiO2-SiO2 glass containing Ba2TiSi2O8 crystal

Hirokazu Masai; Shinji Tsuji; Takumi Fujiwara; Yasuhiko Benino; Takayuki Komatsu

doi:10.1016/j.jnoncrysol.2007.03.005

Structure and non-linear optical properties of BaO-TiO₂-SiO₂ glass containing Ba₂TiSi₂O₈ crystal

Hirokazu Masai, Shinji Tsuji, Takumi Fujiwara, Yasuhiko Benino, Takayuki Komatsu

Research output: Contribution to journal › Article › peer-review

47 Citations (Scopus)

Abstract

The BaO-TiO₂-SiO₂ crystallized glass containing Ba₂TiSi₂O₈ crystal phase was examined using X-ray diffraction (XRD) measurement and Maker fringe technique. It has been found that the crystallized glasses with a composition of close to the stoichiometric Ba₂TiSi₂O₈ showed bulk crystallization, whereas other crystallized glasses with non-stoichiometric composition of Ba₂TiSi₂O₈ showed surface crystallization. The parameter ΔT, the difference in temperature between the crystallization onset and the glass transition temperature, strongly affects the crystallization behaviors of the present BTS glasses. The 30BaO-20TiO₂-50SiO₂ transparent surface crystallized glass with strong c-oriented Ba₂TiSi₂O₈ phase showed its second-order non-linear optical constant, d₃₃ = 6.1 pm/V.

Original language	English
Pages (from-to)	2258-2262
Number of pages	5
Journal	Journal of Non-Crystalline Solids
Volume	353
Issue number	22-23
DOIs	https://doi.org/10.1016/j.jnoncrysol.2007.03.005
Publication status	Published - Jul 1 2007
Externally published	Yes

Keywords

Glass ceramics
Non-linear optics

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Materials Chemistry

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title = "Structure and non-linear optical properties of BaO-TiO2-SiO2 glass containing Ba2TiSi2O8 crystal",

abstract = "The BaO-TiO2-SiO2 crystallized glass containing Ba2TiSi2O8 crystal phase was examined using X-ray diffraction (XRD) measurement and Maker fringe technique. It has been found that the crystallized glasses with a composition of close to the stoichiometric Ba2TiSi2O8 showed bulk crystallization, whereas other crystallized glasses with non-stoichiometric composition of Ba2TiSi2O8 showed surface crystallization. The parameter ΔT, the difference in temperature between the crystallization onset and the glass transition temperature, strongly affects the crystallization behaviors of the present BTS glasses. The 30BaO-20TiO2-50SiO2 transparent surface crystallized glass with strong c-oriented Ba2TiSi2O8 phase showed its second-order non-linear optical constant, d33 = 6.1 pm/V.",

keywords = "Glass ceramics, Non-linear optics",

author = "Hirokazu Masai and Shinji Tsuji and Takumi Fujiwara and Yasuhiko Benino and Takayuki Komatsu",

note = "Funding Information: This work was partially supported by the Grant-in-Aid for Scientific Research from the Ministry of Education, Science, Sport and Culture, Japan, the SCOPE (Strategic Information and Communications R&D Promotion Program) project by the Ministry of Public Management, Home Affairs, Posts and Telecommunications, Japan, the research collaboration with Asahi Glass Co. LTD., and the 21st century Center of Excellence (COE) Program in Nagaoka University of Technology. The authors are grateful to Professor M. Takada, Nagaoka University of Technology, for use of a spectroscopic ellipsometer.",

year = "2007",

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doi = "10.1016/j.jnoncrysol.2007.03.005",

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AU - Masai, Hirokazu

AU - Tsuji, Shinji

AU - Fujiwara, Takumi

AU - Benino, Yasuhiko

AU - Komatsu, Takayuki

N1 - Funding Information: This work was partially supported by the Grant-in-Aid for Scientific Research from the Ministry of Education, Science, Sport and Culture, Japan, the SCOPE (Strategic Information and Communications R&D Promotion Program) project by the Ministry of Public Management, Home Affairs, Posts and Telecommunications, Japan, the research collaboration with Asahi Glass Co. LTD., and the 21st century Center of Excellence (COE) Program in Nagaoka University of Technology. The authors are grateful to Professor M. Takada, Nagaoka University of Technology, for use of a spectroscopic ellipsometer.

PY - 2007/7/1

Y1 - 2007/7/1

N2 - The BaO-TiO2-SiO2 crystallized glass containing Ba2TiSi2O8 crystal phase was examined using X-ray diffraction (XRD) measurement and Maker fringe technique. It has been found that the crystallized glasses with a composition of close to the stoichiometric Ba2TiSi2O8 showed bulk crystallization, whereas other crystallized glasses with non-stoichiometric composition of Ba2TiSi2O8 showed surface crystallization. The parameter ΔT, the difference in temperature between the crystallization onset and the glass transition temperature, strongly affects the crystallization behaviors of the present BTS glasses. The 30BaO-20TiO2-50SiO2 transparent surface crystallized glass with strong c-oriented Ba2TiSi2O8 phase showed its second-order non-linear optical constant, d33 = 6.1 pm/V.

AB - The BaO-TiO2-SiO2 crystallized glass containing Ba2TiSi2O8 crystal phase was examined using X-ray diffraction (XRD) measurement and Maker fringe technique. It has been found that the crystallized glasses with a composition of close to the stoichiometric Ba2TiSi2O8 showed bulk crystallization, whereas other crystallized glasses with non-stoichiometric composition of Ba2TiSi2O8 showed surface crystallization. The parameter ΔT, the difference in temperature between the crystallization onset and the glass transition temperature, strongly affects the crystallization behaviors of the present BTS glasses. The 30BaO-20TiO2-50SiO2 transparent surface crystallized glass with strong c-oriented Ba2TiSi2O8 phase showed its second-order non-linear optical constant, d33 = 6.1 pm/V.

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