Structure and electronic properties of Cs3C60 under ambient pressure revealed by X-ray diffraction and ESR

Yukihiro Yoshida, Yoshihiro Kubozono, Setsuo Kashino, Youichi Murakami

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    14 Citations (Scopus)

    Abstract

    The structure and electronic properties of Cs3C60 under ambient pressure were studied by X-ray diffraction (XRD) and ESR. The XRD showed that Cs3C60 takes a body-centered orthorhombic structure as the main phase. No clear structural change was observed down to 9 K. The temperature dependence of the ESR peak suggested that Cs3C60 exhibits a metallic behavior but no metal-insulator transition down to 1.9 K, contrary to a previous prediction.

    Original languageEnglish
    Pages (from-to)31-36
    Number of pages6
    JournalChemical Physics Letters
    Volume291
    Issue number1-2
    DOIs
    Publication statusPublished - Jul 10 1998

    ASJC Scopus subject areas

    • Physics and Astronomy(all)
    • Physical and Theoretical Chemistry

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