Structure and electronic properties of Cs3C60 under ambient pressure revealed by X-ray diffraction and ESR

Yukihiro Yoshida, Yoshihiro Kubozono, Setsuo Kashino, Youichi Murakami

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

The structure and electronic properties of Cs3C60 under ambient pressure were studied by X-ray diffraction (XRD) and ESR. The XRD showed that Cs3C60 takes a body-centered orthorhombic structure as the main phase. No clear structural change was observed down to 9 K. The temperature dependence of the ESR peak suggested that Cs3C60 exhibits a metallic behavior but no metal-insulator transition down to 1.9 K, contrary to a previous prediction.

Original languageEnglish
Pages (from-to)31-36
Number of pages6
JournalChemical Physics Letters
Volume291
Issue number1-2
Publication statusPublished - Jul 10 1998

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Electronic properties
Paramagnetic resonance
X ray diffraction
Metal insulator transition
electronics
diffraction
x rays
insulators
temperature dependence
predictions
metals
Temperature

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics

Cite this

Structure and electronic properties of Cs3C60 under ambient pressure revealed by X-ray diffraction and ESR. / Yoshida, Yukihiro; Kubozono, Yoshihiro; Kashino, Setsuo; Murakami, Youichi.

In: Chemical Physics Letters, Vol. 291, No. 1-2, 10.07.1998, p. 31-36.

Research output: Contribution to journalArticle

Yoshida, Yukihiro ; Kubozono, Yoshihiro ; Kashino, Setsuo ; Murakami, Youichi. / Structure and electronic properties of Cs3C60 under ambient pressure revealed by X-ray diffraction and ESR. In: Chemical Physics Letters. 1998 ; Vol. 291, No. 1-2. pp. 31-36.
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