Structure and Dynamic Behavior of Sodium-Diglyme Complex in the Graphite Anode of Sodium Ion Battery by 2H Nuclear Magnetic Resonance

Kazuma Gotoh, Hisashi Maruyama, Tatsuya Miyatou, Motohiro Mizuno, Koki Urita, Hiroyuki Ishida

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Cointercalation systems consisting of graphite, sodium, and some linear glycol ethers (glymes) are anticipated for use as negative electrodes in sodium ion batteries because of their superior properties such as outstanding cycle performance. We synthesized a ternary intercalation compound consisting of sodium, deuterated diglyme (diglyme-d14), and graphite by a solution reaction. Then we investigated the dynamics and coordination structure of diglyme-d14 molecules by 2H solid-state NMR. Two diglyme molecules coordinate to each sodium ion rigidly, except for rotation of the methyl groups at low temperatures below 233 K. At room temperature, diglyme weakly coordinates to a Na ion through one oxygen atom of the ligand and rotates around the O-Na axis. The active motion of sodium-diglyme complexes is favorable for Na diffusion between graphene layers in the graphite intercalation compound. (Figure Presented).

Original languageEnglish
Pages (from-to)28152-28156
Number of pages5
JournalJournal of Physical Chemistry C
Volume120
Issue number49
DOIs
Publication statusPublished - Dec 15 2016

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Graphite
electric batteries
Anodes
anodes
graphite
Sodium
Nuclear magnetic resonance
sodium
Ions
nuclear magnetic resonance
Intercalation compounds
ions
intercalation
Sodium Compounds
Molecules
Glycols
Ethers
Graphene
glycols
molecules

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Surfaces, Coatings and Films
  • Physical and Theoretical Chemistry

Cite this

Structure and Dynamic Behavior of Sodium-Diglyme Complex in the Graphite Anode of Sodium Ion Battery by 2H Nuclear Magnetic Resonance. / Gotoh, Kazuma; Maruyama, Hisashi; Miyatou, Tatsuya; Mizuno, Motohiro; Urita, Koki; Ishida, Hiroyuki.

In: Journal of Physical Chemistry C, Vol. 120, No. 49, 15.12.2016, p. 28152-28156.

Research output: Contribution to journalArticle

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AU - Gotoh, Kazuma

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AU - Urita, Koki

AU - Ishida, Hiroyuki

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AB - Cointercalation systems consisting of graphite, sodium, and some linear glycol ethers (glymes) are anticipated for use as negative electrodes in sodium ion batteries because of their superior properties such as outstanding cycle performance. We synthesized a ternary intercalation compound consisting of sodium, deuterated diglyme (diglyme-d14), and graphite by a solution reaction. Then we investigated the dynamics and coordination structure of diglyme-d14 molecules by 2H solid-state NMR. Two diglyme molecules coordinate to each sodium ion rigidly, except for rotation of the methyl groups at low temperatures below 233 K. At room temperature, diglyme weakly coordinates to a Na ion through one oxygen atom of the ligand and rotates around the O-Na axis. The active motion of sodium-diglyme complexes is favorable for Na diffusion between graphene layers in the graphite intercalation compound. (Figure Presented).

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