Structural relaxation kinetics of antimony borate glasses with covalent bonding character

T. Honma; Y. Benino; T. Komatsu; R. Sato; V. Dimitrov

doi:10.1063/1.1404990

Structural relaxation kinetics of antimony borate glasses with covalent bonding character

T. Honma, Y. Benino, T. Komatsu, R. Sato, V. Dimitrov

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11 Citations (Scopus)

Abstract

The structural relaxation kinetics in the glass transition region for xSb₂O₃·(100-x)B₂O₃ glasses were examined from viscosity and heat capacity measurements. The aim was to clarify the correlation between the relaxation kinetics and the Sb-O chemical bonding state. It was shown that the structural relaxation kinetics of the binary antimony borate glasses is affected by boron coordination numbers and the covalent bonding character of Sb-O bonds, and consequently these glasses are regarded as a highly strong glass-forming system in the fragile/strong classification concept.

Original language	English
Pages (from-to)	7207-7214
Number of pages	8
Journal	Journal of Chemical Physics
Volume	115
Issue number	15
DOIs	https://doi.org/10.1063/1.1404990
Publication status	Published - Oct 15 2001
Externally published	Yes

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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abstract = "The structural relaxation kinetics in the glass transition region for xSb2O3·(100-x)B2O3 glasses were examined from viscosity and heat capacity measurements. The aim was to clarify the correlation between the relaxation kinetics and the Sb-O chemical bonding state. It was shown that the structural relaxation kinetics of the binary antimony borate glasses is affected by boron coordination numbers and the covalent bonding character of Sb-O bonds, and consequently these glasses are regarded as a highly strong glass-forming system in the fragile/strong classification concept.",

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AU - Honma, T.

AU - Benino, Y.

AU - Komatsu, T.

AU - Sato, R.

AU - Dimitrov, V.

PY - 2001/10/15

Y1 - 2001/10/15

N2 - The structural relaxation kinetics in the glass transition region for xSb2O3·(100-x)B2O3 glasses were examined from viscosity and heat capacity measurements. The aim was to clarify the correlation between the relaxation kinetics and the Sb-O chemical bonding state. It was shown that the structural relaxation kinetics of the binary antimony borate glasses is affected by boron coordination numbers and the covalent bonding character of Sb-O bonds, and consequently these glasses are regarded as a highly strong glass-forming system in the fragile/strong classification concept.

AB - The structural relaxation kinetics in the glass transition region for xSb2O3·(100-x)B2O3 glasses were examined from viscosity and heat capacity measurements. The aim was to clarify the correlation between the relaxation kinetics and the Sb-O chemical bonding state. It was shown that the structural relaxation kinetics of the binary antimony borate glasses is affected by boron coordination numbers and the covalent bonding character of Sb-O bonds, and consequently these glasses are regarded as a highly strong glass-forming system in the fragile/strong classification concept.

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Structural relaxation kinetics of antimony borate glasses with covalent bonding character

Abstract

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