Seven solid phases including three metastable phases of (CH3)3CNH3N03 were revealed by differential thermal analysis in the temperature range between 80 K and the melting point (418 K), and cationic dynamics in each phase was studied by use of 1 H-NMR techniques. The highest-temperature solid phase obtainable above 412 K was found to be an ionic plastic phase, where the cations perform rapid translational self-diffusion and overall rotation about their center of gravity.
|Number of pages||4|
|Journal||Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences|
|Publication status||Published - Jan 1 1989|
ASJC Scopus subject areas
- Mathematical Physics
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry