TY - JOUR
T1 - Structural Phase Transitions in Solid tert-Butylammonium Nitrate as Studied by Differential Thermal Analysis and 1H-NMR
AU - Ishida, Hiroyuki
AU - Iwachido, Tadashi
AU - Hayama, Naomi
AU - Ikeda, Ryuichi
AU - Hashimoto, Miyuki
AU - Nakamura, Daiyu
PY - 1989/1/1
Y1 - 1989/1/1
N2 - Seven solid phases including three metastable phases of (CH3)3CNH3N03 were revealed by differential thermal analysis in the temperature range between 80 K and the melting point (418 K), and cationic dynamics in each phase was studied by use of 1 H-NMR techniques. The highest-temperature solid phase obtainable above 412 K was found to be an ionic plastic phase, where the cations perform rapid translational self-diffusion and overall rotation about their center of gravity.
AB - Seven solid phases including three metastable phases of (CH3)3CNH3N03 were revealed by differential thermal analysis in the temperature range between 80 K and the melting point (418 K), and cationic dynamics in each phase was studied by use of 1 H-NMR techniques. The highest-temperature solid phase obtainable above 412 K was found to be an ionic plastic phase, where the cations perform rapid translational self-diffusion and overall rotation about their center of gravity.
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U2 - 10.1515/zna-1989-0113
DO - 10.1515/zna-1989-0113
M3 - Article
AN - SCOPUS:84872089191
SN - 0932-0784
VL - 44
SP - 71
EP - 74
JO - Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences
JF - Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences
IS - 1
ER -