Structural phase transition in two-dimensional crystallites of organic dye molecules formed on aqueous subphases

Noritaka Kato; Ichiro Hirosawa; Masugu Sato; Naoshi Ikeda; Ken Ichi Iimura; Yoshiaki Uesu

doi:10.1080/00150190601182477

Structural phase transition in two-dimensional crystallites of organic dye molecules formed on aqueous subphases

Noritaka Kato, Ichiro Hirosawa, Masugu Sato, Naoshi Ikeda, Ken Ichi Iimura, Yoshiaki Uesu

Research output: Contribution to journal › Conference article › peer-review

1 Citation (Scopus)

Abstract

The 2D crystallites of polar organic dye molecules on an aqueous subphase exhibit a thermochromic phase transition. The visible absorption band of the crystallites depends on the temperature and the composition of the subphase. In-situ observations of the phase transition were carried out by a grazing incidence X-ray diffraction method. A shift and a split of the diffraction peaks were observed between the different phases, indicating a change in the molecular arrangement of the crystallites in their chromic transition.

Original language	English
Pages (from-to)	162-167
Number of pages	6
Journal	Ferroelectrics
Volume	346
DOIs	https://doi.org/10.1080/00150190601182477
Publication status	Published - 2007
Event	8th Russia/CIS/Baltic/Japan Symposium on Ferroelectricity, RCBJSF-8 - Tsukuba, Japan Duration: May 15 2006 → May 19 2006

Keywords

Grazing incidence X-ray diffraction
J-aggregate
Merocyanine dye
Monolayer at the air-water interface; Langmuir film
Synchrotron radiation

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics

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10.1080/00150190601182477

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@article{51c1dc839f394231b7c38fb174658eee,

title = "Structural phase transition in two-dimensional crystallites of organic dye molecules formed on aqueous subphases",

abstract = "The 2D crystallites of polar organic dye molecules on an aqueous subphase exhibit a thermochromic phase transition. The visible absorption band of the crystallites depends on the temperature and the composition of the subphase. In-situ observations of the phase transition were carried out by a grazing incidence X-ray diffraction method. A shift and a split of the diffraction peaks were observed between the different phases, indicating a change in the molecular arrangement of the crystallites in their chromic transition.",

keywords = "Grazing incidence X-ray diffraction, J-aggregate, Merocyanine dye, Monolayer at the air-water interface; Langmuir film, Synchrotron radiation",

author = "Noritaka Kato and Ichiro Hirosawa and Masugu Sato and Naoshi Ikeda and Iimura, {Ken Ichi} and Yoshiaki Uesu",

note = "Funding Information: The measurements using synchrotron radiation were performed at the SPring-8 with the approval of the Japan Synchrotron Research Institute (JASRI) (Proposal No. 2003B0222-ND1d-np and 2005B0246). This work was supported by the Saneyoshi Scholarship Foundation, Grants-in-Aid for Young Scientists (B) (17760015, 2005), and The 21st Century COE Program (Physics of Self-Organization Systems) at Waseda University from MEXT, Japan.; 8th Russia/CIS/Baltic/Japan Symposium on Ferroelectricity, RCBJSF-8 ; Conference date: 15-05-2006 Through 19-05-2006",

year = "2007",

doi = "10.1080/00150190601182477",

language = "English",

volume = "346",

pages = "162--167",

journal = "Ferroelectrics",

issn = "0015-0193",

publisher = "Taylor and Francis Ltd.",

}

TY - JOUR

T1 - Structural phase transition in two-dimensional crystallites of organic dye molecules formed on aqueous subphases

AU - Kato, Noritaka

AU - Hirosawa, Ichiro

AU - Sato, Masugu

AU - Ikeda, Naoshi

AU - Iimura, Ken Ichi

AU - Uesu, Yoshiaki

N1 - Funding Information: The measurements using synchrotron radiation were performed at the SPring-8 with the approval of the Japan Synchrotron Research Institute (JASRI) (Proposal No. 2003B0222-ND1d-np and 2005B0246). This work was supported by the Saneyoshi Scholarship Foundation, Grants-in-Aid for Young Scientists (B) (17760015, 2005), and The 21st Century COE Program (Physics of Self-Organization Systems) at Waseda University from MEXT, Japan.

PY - 2007

Y1 - 2007

N2 - The 2D crystallites of polar organic dye molecules on an aqueous subphase exhibit a thermochromic phase transition. The visible absorption band of the crystallites depends on the temperature and the composition of the subphase. In-situ observations of the phase transition were carried out by a grazing incidence X-ray diffraction method. A shift and a split of the diffraction peaks were observed between the different phases, indicating a change in the molecular arrangement of the crystallites in their chromic transition.

AB - The 2D crystallites of polar organic dye molecules on an aqueous subphase exhibit a thermochromic phase transition. The visible absorption band of the crystallites depends on the temperature and the composition of the subphase. In-situ observations of the phase transition were carried out by a grazing incidence X-ray diffraction method. A shift and a split of the diffraction peaks were observed between the different phases, indicating a change in the molecular arrangement of the crystallites in their chromic transition.

KW - Grazing incidence X-ray diffraction

KW - J-aggregate

KW - Merocyanine dye

KW - Monolayer at the air-water interface; Langmuir film

KW - Synchrotron radiation

UR - http://www.scopus.com/inward/record.url?scp=34547284908&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=34547284908&partnerID=8YFLogxK

U2 - 10.1080/00150190601182477

DO - 10.1080/00150190601182477

M3 - Conference article

AN - SCOPUS:34547284908

VL - 346

SP - 162

EP - 167

JO - Ferroelectrics

JF - Ferroelectrics

SN - 0015-0193

T2 - 8th Russia/CIS/Baltic/Japan Symposium on Ferroelectricity, RCBJSF-8

Y2 - 15 May 2006 through 19 May 2006

ER -

Structural phase transition in two-dimensional crystallites of organic dye molecules formed on aqueous subphases

Abstract

Keywords

ASJC Scopus subject areas

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