Structural analysis of molten PbCl2

Hideki Morikawa; Michihiro Miyake; Yoshiki Takagi; Fumiyuki Marumo

doi:10.1039/F19817701967

Structural analysis of molten PbCl₂

Hideki Morikawa, Michihiro Miyake, Yoshiki Takagi, Fumiyuki Marumo

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

The structure of molten PbCl₂ has been re-examined by X-ray diffraction analysis. In molten PbCl₂, each Pb atom is surrounded by three Cl atoms at an average distance of 2.63 Å as well as four Cl atoms of 3.14 Å. The average Pb-Pb interaction within 10 Å is similar to a distorted f.c.c. arrangement.

Original language	English
Pages (from-to)	1967-1972
Number of pages	6
Journal	Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
Volume	77
Issue number	8
DOIs	https://doi.org/10.1039/F19817701967
Publication status	Published - Dec 1 1981
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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abstract = "The structure of molten PbCl2 has been re-examined by X-ray diffraction analysis. In molten PbCl2, each Pb atom is surrounded by three Cl atoms at an average distance of 2.63 {\AA} as well as four Cl atoms of 3.14 {\AA}. The average Pb-Pb interaction within 10 {\AA} is similar to a distorted f.c.c. arrangement.",

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AB - The structure of molten PbCl2 has been re-examined by X-ray diffraction analysis. In molten PbCl2, each Pb atom is surrounded by three Cl atoms at an average distance of 2.63 Å as well as four Cl atoms of 3.14 Å. The average Pb-Pb interaction within 10 Å is similar to a distorted f.c.c. arrangement.

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