Structural analysis of molten B2O3

Michihiro Miyake; Takashi Suzuki; Hideki Morikawa; Yoshiki Takagi; Fumiyuki Marumo

doi:10.1039/F19848001925

Structural analysis of molten B₂O₃

Michihiro Miyake, Takashi Suzuki, Hideki Morikawa, Yoshiki Takagi, Fumiyuki Marumo

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21 Citations (Scopus)

Abstract

The structure of molten B₂O₃ at ca. 650 °C has been investigated by the X-ray radial distribution method. The most likely two-dimensional quasi-crystalline model for the short-range arrangement is a mixed structure of boroxol rings and independent BO₃ triangles. The estimated density for this model with an average inter-layer distance of 4.34 Å is in good agreement with the observed density.

Original language	English
Pages (from-to)	1925-1931
Number of pages	7
Journal	Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
Volume	80
Issue number	7
DOIs	https://doi.org/10.1039/F19848001925
Publication status	Published - 1984
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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10.1039/F19848001925

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title = "Structural analysis of molten B2O3",

abstract = "The structure of molten B2O3 at ca. 650 °C has been investigated by the X-ray radial distribution method. The most likely two-dimensional quasi-crystalline model for the short-range arrangement is a mixed structure of boroxol rings and independent BO3 triangles. The estimated density for this model with an average inter-layer distance of 4.34 {\AA} is in good agreement with the observed density.",

author = "Michihiro Miyake and Takashi Suzuki and Hideki Morikawa and Yoshiki Takagi and Fumiyuki Marumo",

year = "1984",

doi = "10.1039/F19848001925",

language = "English",

volume = "80",

pages = "1925--1931",

journal = "Physical Chemistry Chemical Physics",

issn = "1463-9076",

publisher = "Royal Society of Chemistry",

number = "7",

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TY - JOUR

T1 - Structural analysis of molten B2O3

AU - Miyake, Michihiro

AU - Suzuki, Takashi

AU - Morikawa, Hideki

AU - Takagi, Yoshiki

AU - Marumo, Fumiyuki

PY - 1984

Y1 - 1984

N2 - The structure of molten B2O3 at ca. 650 °C has been investigated by the X-ray radial distribution method. The most likely two-dimensional quasi-crystalline model for the short-range arrangement is a mixed structure of boroxol rings and independent BO3 triangles. The estimated density for this model with an average inter-layer distance of 4.34 Å is in good agreement with the observed density.

AB - The structure of molten B2O3 at ca. 650 °C has been investigated by the X-ray radial distribution method. The most likely two-dimensional quasi-crystalline model for the short-range arrangement is a mixed structure of boroxol rings and independent BO3 triangles. The estimated density for this model with an average inter-layer distance of 4.34 Å is in good agreement with the observed density.

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U2 - 10.1039/F19848001925

DO - 10.1039/F19848001925

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EP - 1931

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

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ER -

Structural analysis of molten B₂O₃

Abstract

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