Structural analysis of molten B2O3

Michihiro Miyake, Takashi Suzuki, Hideki Morikawa, Yoshiki Takagi, Fumiyuki Marumo

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Abstract

The structure of molten B2O3 at ca. 650 °C has been investigated by the X-ray radial distribution method. The most likely two-dimensional quasi-crystalline model for the short-range arrangement is a mixed structure of boroxol rings and independent BO3 triangles. The estimated density for this model with an average inter-layer distance of 4.34 Å is in good agreement with the observed density.

Original languageEnglish
Pages (from-to)1925-1931
Number of pages7
JournalJournal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
Volume80
Issue number7
DOIs
Publication statusPublished - Jan 1 1984

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ASJC Scopus subject areas

  • Chemistry(all)

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