Structural analysis of molten B2O3

Michihiro Miyake; Takashi Suzuki; Hideki Morikawa; Yoshiki Takagi; Fumiyuki Marumo

doi:10.1039/F19848001925

Structural analysis of molten B₂O₃

Michihiro Miyake, Takashi Suzuki, Hideki Morikawa, Yoshiki Takagi, Fumiyuki Marumo

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

The structure of molten B₂O₃ at ca. 650 °C has been investigated by the X-ray radial distribution method. The most likely two-dimensional quasi-crystalline model for the short-range arrangement is a mixed structure of boroxol rings and independent BO₃ triangles. The estimated density for this model with an average inter-layer distance of 4.34 Å is in good agreement with the observed density.

Original language	English
Pages (from-to)	1925-1931
Number of pages	7
Journal	Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
Volume	80
Issue number	7
DOIs	https://doi.org/10.1039/F19848001925
Publication status	Published - Jan 1 1984
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1039/F19848001925

Fingerprint Dive into the research topics of 'Structural analysis of molten B<sub>2</sub>O<sub>3</sub>'. Together they form a unique fingerprint.

Cite this

@article{00b7c66fd25e486fae280544dc0f5b48,

title = "Structural analysis of molten B2O3",

abstract = "The structure of molten B2O3 at ca. 650 °C has been investigated by the X-ray radial distribution method. The most likely two-dimensional quasi-crystalline model for the short-range arrangement is a mixed structure of boroxol rings and independent BO3 triangles. The estimated density for this model with an average inter-layer distance of 4.34 {\AA} is in good agreement with the observed density.",

author = "Michihiro Miyake and Takashi Suzuki and Hideki Morikawa and Yoshiki Takagi and Fumiyuki Marumo",

year = "1984",

month = jan,

day = "1",

doi = "10.1039/F19848001925",

language = "English",

volume = "80",

pages = "1925--1931",

journal = "Physical Chemistry Chemical Physics",

issn = "1463-9076",

publisher = "Royal Society of Chemistry",

number = "7",

}

TY - JOUR

T1 - Structural analysis of molten B2O3

AU - Miyake, Michihiro

AU - Suzuki, Takashi

AU - Morikawa, Hideki

AU - Takagi, Yoshiki

AU - Marumo, Fumiyuki

PY - 1984/1/1

Y1 - 1984/1/1

N2 - The structure of molten B2O3 at ca. 650 °C has been investigated by the X-ray radial distribution method. The most likely two-dimensional quasi-crystalline model for the short-range arrangement is a mixed structure of boroxol rings and independent BO3 triangles. The estimated density for this model with an average inter-layer distance of 4.34 Å is in good agreement with the observed density.

AB - The structure of molten B2O3 at ca. 650 °C has been investigated by the X-ray radial distribution method. The most likely two-dimensional quasi-crystalline model for the short-range arrangement is a mixed structure of boroxol rings and independent BO3 triangles. The estimated density for this model with an average inter-layer distance of 4.34 Å is in good agreement with the observed density.

UR - http://www.scopus.com/inward/record.url?scp=37049113713&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=37049113713&partnerID=8YFLogxK

U2 - 10.1039/F19848001925

DO - 10.1039/F19848001925

M3 - Article

AN - SCOPUS:37049113713

VL - 80

SP - 1925

EP - 1931

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

SN - 1463-9076

IS - 7