Structural analysis of molten B2O3

Michihiro Miyake; Takashi Suzuki; Hideki Morikawa; Yoshiki Takagi; Fumiyuki Marumo

doi:10.1039/F19848001925

Structural analysis of molten B₂O₃

Michihiro Miyake, Takashi Suzuki, Hideki Morikawa, Yoshiki Takagi, Fumiyuki Marumo

Research output: Contribution to journal › Article

21 Citations (Scopus)

Abstract

The structure of molten B₂O₃ at ca. 650 °C has been investigated by the X-ray radial distribution method. The most likely two-dimensional quasi-crystalline model for the short-range arrangement is a mixed structure of boroxol rings and independent BO₃ triangles. The estimated density for this model with an average inter-layer distance of 4.34 Å is in good agreement with the observed density.

Original language	English
Pages (from-to)	1925-1931
Number of pages	7
Journal	Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
Volume	80
Issue number	7
DOIs	https://doi.org/10.1039/F19848001925
Publication status	Published - Jan 1 1984
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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10.1039/F19848001925

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Miyake, M., Suzuki, T., Morikawa, H., Takagi, Y., & Marumo, F. (1984). Structural analysis of molten B₂O₃. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 80(7), 1925-1931. https://doi.org/10.1039/F19848001925

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