Strain-release difunctionalization of CC σ- And π-bonds of an Organoboron Ate-complex through 1,2-Metallate Rearrangement

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Abstract

This highlight review describes the recent development of an electrophile-triggered 1,2-metallate rearrangement of organoboronic ester ate-complex, which proceeds through 1,2-difunctionalization of carboncarbon σ- and π-bonds, using strain energy as a driving force. Coupling reactions of small ring carbocyclic boronic esters, such as cyclopropyl-, bicyclo[1.1.0]- butyl-, and cyclopropenyl-boronic ester, are summarized along with the proposed reaction mechanisms and representative examples.

Original languageEnglish
Pages (from-to)792-799
Number of pages8
JournalChemistry Letters
Volume50
Issue number4
DOIs
Publication statusPublished - Apr 2021

Keywords

  • 1,2-Metallate rearrangement
  • Boronic ester ate-complex
  • Ring strain

ASJC Scopus subject areas

  • Chemistry(all)

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