Stereospecific reduction of menthyloxyphosphine-boranes with one-electron reducing agents

Toshiyuki Oshiki, Takaaki Hikosaka, Tsuneo Imamoto

Research output: Contribution to journalArticle

44 Citations (Scopus)

Abstract

The phosphorus-oxygen bond of diastereomerically pure menthyloxyphosphine-boranes was reductively cleaved at -78 °C by lithium naphthalenide or Li-NH3 in excellent yields wilh almost complete retention of configuration at phosphorus.

Original languageEnglish
Pages (from-to)3371-3374
Number of pages4
JournalTetrahedron Letters
Volume32
Issue number28
DOIs
Publication statusPublished - Jul 8 1991
Externally publishedYes

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Boranes
Reducing Agents
Phosphorus
Electrons
Lithium
Oxygen

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Stereospecific reduction of menthyloxyphosphine-boranes with one-electron reducing agents. / Oshiki, Toshiyuki; Hikosaka, Takaaki; Imamoto, Tsuneo.

In: Tetrahedron Letters, Vol. 32, No. 28, 08.07.1991, p. 3371-3374.

Research output: Contribution to journalArticle

Oshiki, Toshiyuki ; Hikosaka, Takaaki ; Imamoto, Tsuneo. / Stereospecific reduction of menthyloxyphosphine-boranes with one-electron reducing agents. In: Tetrahedron Letters. 1991 ; Vol. 32, No. 28. pp. 3371-3374.
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