Abstract
Vinyl-substituted (Z)-stilbenes are stereoselectively synthesised on treatment of 4-arylbuta-2,3-dien-1-ols with arylboronic acids in the presence of a rhodium(i) catalyst. The reaction proceeds through the regioselective addition of organorhodium(i) species across the aryl-substituted carbon-carbon double bond of the allene moiety and subsequent δ-elimination of Rh(i)-OH.
Original language | English |
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Pages (from-to) | 4074-4076 |
Number of pages | 3 |
Journal | Organic and Biomolecular Chemistry |
Volume | 8 |
Issue number | 18 |
DOIs | |
Publication status | Published - Sep 21 2010 |
Externally published | Yes |
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry