Stereoselective synthesis of the C79-C97 fragment of symbiodinolide

Hiroyoshi Takamura, Takayuki Fujiwara, Isao Kadota, Daisuke Uemura

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Symbiodinolide is a polyol marine natural product with a molecular weight of 2860. Herein, a streamlined synthesis of the C79-C97 fragment of symbiodinolide is described. In the synthetic route, a spiroacetalization, a Julia-Kocienski olefination, and a Sharpless asymmetric dihydroxylation were utilized as the key transformations.

Original languageEnglish
Pages (from-to)1931-1935
Number of pages5
JournalBeilstein Journal of Organic Chemistry
Volume9
DOIs
Publication statusPublished - Sep 25 2013

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Keywords

  • Julia-Kocienski olefination
  • Polyol marine natural product
  • Sharpless asymmetric dihydroxylation
  • Spiroacetalization
  • Symbiodinolide

ASJC Scopus subject areas

  • Organic Chemistry

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