Stereoselective preparation of primary (E)-allylic amines by the reaction of tantalum-alkyne complexes with metallo-imines

Kazuhiko Takai; Hidetoshi Odaka; Yasutaka Kataoka; Kiitiro Utimoto

doi:10.1016/S0040-4039(00)73189-3

Stereoselective preparation of primary (E)-allylic amines by the reaction of tantalum-alkyne complexes with metallo-imines

Kazuhiko Takai, Hidetoshi Odaka, Yasutaka Kataoka, Kiitiro Utimoto

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Treatment of tantalum-alkyne complexes with lithio-imines at 25∼50°C for several hours in the presence of Me₃Al gives primary (E)-allylic amines having adjacent tertiary carbons in good to excellent yields.

Original language	English
Pages (from-to)	1893-1896
Number of pages	4
Journal	Tetrahedron Letters
Volume	35
Issue number	12
DOIs	https://doi.org/10.1016/S0040-4039(00)73189-3
Publication status	Published - Mar 21 1994
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)73189-3

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title = "Stereoselective preparation of primary (E)-allylic amines by the reaction of tantalum-alkyne complexes with metallo-imines",

abstract = "Treatment of tantalum-alkyne complexes with lithio-imines at 25∼50°C for several hours in the presence of Me3Al gives primary (E)-allylic amines having adjacent tertiary carbons in good to excellent yields.",

author = "Kazuhiko Takai and Hidetoshi Odaka and Yasutaka Kataoka and Kiitiro Utimoto",

year = "1994",

month = mar,

day = "21",

doi = "10.1016/S0040-4039(00)73189-3",

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volume = "35",

pages = "1893--1896",

journal = "Tetrahedron Letters",

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T1 - Stereoselective preparation of primary (E)-allylic amines by the reaction of tantalum-alkyne complexes with metallo-imines

AU - Takai, Kazuhiko

AU - Odaka, Hidetoshi

AU - Kataoka, Yasutaka

AU - Utimoto, Kiitiro

PY - 1994/3/21

Y1 - 1994/3/21

N2 - Treatment of tantalum-alkyne complexes with lithio-imines at 25∼50°C for several hours in the presence of Me3Al gives primary (E)-allylic amines having adjacent tertiary carbons in good to excellent yields.

AB - Treatment of tantalum-alkyne complexes with lithio-imines at 25∼50°C for several hours in the presence of Me3Al gives primary (E)-allylic amines having adjacent tertiary carbons in good to excellent yields.

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U2 - 10.1016/S0040-4039(00)73189-3

DO - 10.1016/S0040-4039(00)73189-3

M3 - Article

AN - SCOPUS:0028265467

SN - 0040-4039

VL - 35

SP - 1893

EP - 1896

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 12

ER -

Stereoselective preparation of primary (E)-allylic amines by the reaction of tantalum-alkyne complexes with metallo-imines

Abstract

ASJC Scopus subject areas

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