Stereoselective construction of quaternary carbons by the reaction of aldehydes with allylic chromium reagents prepared from 1,3-diene monoepoxides and crCl2

Osamu Fujimura, Kazuhiko Takai, Kiitiro Utimoto

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31 Citations (Scopus)

Abstract

A vinyl-substituted δ-hydroxy carbanion synthon is produced by reduction of 1,3-diene monoepoxide with CrCl2 in the presence of LiI. The reagent reacts with aldehydes to afford R*,R* adducts stereoselectively.

Original languageEnglish
Pages (from-to)1705-1706
Number of pages2
JournalJournal of Organic Chemistry
Volume55
Issue number6
Publication statusPublished - 1990
Externally publishedYes

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Chromium
Aldehydes
Carbon

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

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title = "Stereoselective construction of quaternary carbons by the reaction of aldehydes with allylic chromium reagents prepared from 1,3-diene monoepoxides and crCl2",
abstract = "A vinyl-substituted δ-hydroxy carbanion synthon is produced by reduction of 1,3-diene monoepoxide with CrCl2 in the presence of LiI. The reagent reacts with aldehydes to afford R*,R* adducts stereoselectively.",
author = "Osamu Fujimura and Kazuhiko Takai and Kiitiro Utimoto",
year = "1990",
language = "English",
volume = "55",
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journal = "Journal of Organic Chemistry",
issn = "0022-3263",
publisher = "American Chemical Society",
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T1 - Stereoselective construction of quaternary carbons by the reaction of aldehydes with allylic chromium reagents prepared from 1,3-diene monoepoxides and crCl2

AU - Fujimura, Osamu

AU - Takai, Kazuhiko

AU - Utimoto, Kiitiro

PY - 1990

Y1 - 1990

N2 - A vinyl-substituted δ-hydroxy carbanion synthon is produced by reduction of 1,3-diene monoepoxide with CrCl2 in the presence of LiI. The reagent reacts with aldehydes to afford R*,R* adducts stereoselectively.

AB - A vinyl-substituted δ-hydroxy carbanion synthon is produced by reduction of 1,3-diene monoepoxide with CrCl2 in the presence of LiI. The reagent reacts with aldehydes to afford R*,R* adducts stereoselectively.

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M3 - Article

AN - SCOPUS:0001418094

VL - 55

SP - 1705

EP - 1706

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

SN - 0022-3263

IS - 6

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