Stereoselective Construction of Quaternary Carbons by the Reaction of Aldehydes with Allylic Chromium Reagents Prepared from 1,3-Diene Monoepoxides and CrCl2

Osamu Fujimura, Kazuhiko Takai, Kiitiro Utimoto

Research output: Contribution to journalArticle

32 Citations (Scopus)

Abstract

A vinyl-substituted (3-hydroxy carbanion syn-thon is produced by reduction of 1,3-diene monoepoxide with CrCl2 in the presence of Lil. The reagent reacts with aldehydes to afford R*,R* adducts stereoselectively.

Original languageEnglish
Pages (from-to)1705-1706
Number of pages2
JournalJournal of Organic Chemistry
Volume55
Issue number6
DOIs
Publication statusPublished - Jan 1 1990
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry

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