Stereodivergent hydrosilylation of 1-alkynes catalyzed by RhI (PPh3)3 leading to (E)- and (Z)-alkenylsilanes and the application to polymer synthesis

Atsunori Mori, Eisuke Takahisa, Hiroshi Kajiro, Yasushi Nishihara, Tamejiro Hiyama

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24 Citations (Scopus)

Abstract

Hydrosilylation of 1-alkynes catalyzed by RhI(PPh3)3 gives (E)- and (Z)-alkenylsilanes in a stereodivergent manner by switching the reaction conditions and the order of the addition of the reagents. The reaction is also applied to the synthesis of silicon-containing polymers with (E) and (Z) main-chain structures via polyaddition. (C) 2000 Elsevier Science Ltd All rights reserved.

Original languageEnglish
Pages (from-to)567-568
Number of pages2
JournalPolyhedron
Volume19
Issue number5
DOIs
Publication statusPublished - Mar 15 2000
Externally publishedYes

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Keywords

  • Alkenylsilanes
  • Hydrosilylation
  • Polyaddition
  • RhI(PPh)
  • Stereodivergent

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

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