Stereochemistry of a Unique Tricarbocyclic Compound Prepared by Superacid-Catalyzed Cyclization

Hisahide Tanimoto; Hiromasa Kiyota; Takayuki Oritani; Keita Matsumoto

Stereochemistry of a Unique Tricarbocyclic Compound Prepared by Superacid-Catalyzed Cyclization

Hisahide Tanimoto, Hiromasa Kiyota, Takayuki Oritani, Keita Matsumoto

Research output: Contribution to journal › Article

Abstract

Chlorosulfonic acid catalyzed cyclization reaction of β-monocyclonerolidol and β-monocyclofarnesol and corresponding acetates gave a unique rearranged product (2S*, 3S*, 4aR*, 8aS*)-1, 3, 4, 5, 6, 7, 8, 8a-octahydro-2, 5, 5, 8a-tetramethyl-2H-2, 4a-methanonaphthalen-3-ol, the structure of which was elucidated by X-ray analysis.

Original language	English
Pages (from-to)	121-122
Number of pages	2
Journal	Synlett
Volume	1997
Issue number	1
Publication status	Published - Dec 1 1997
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry

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title = "Stereochemistry of a Unique Tricarbocyclic Compound Prepared by Superacid-Catalyzed Cyclization",

abstract = "Chlorosulfonic acid catalyzed cyclization reaction of β-monocyclonerolidol and β-monocyclofarnesol and corresponding acetates gave a unique rearranged product (2S*, 3S*, 4aR*, 8aS*)-1, 3, 4, 5, 6, 7, 8, 8a-octahydro-2, 5, 5, 8a-tetramethyl-2H-2, 4a-methanonaphthalen-3-ol, the structure of which was elucidated by X-ray analysis.",

author = "Hisahide Tanimoto and Hiromasa Kiyota and Takayuki Oritani and Keita Matsumoto",

year = "1997",

month = dec,

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language = "English",

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T1 - Stereochemistry of a Unique Tricarbocyclic Compound Prepared by Superacid-Catalyzed Cyclization

AU - Tanimoto, Hisahide

AU - Kiyota, Hiromasa

AU - Oritani, Takayuki

AU - Matsumoto, Keita

PY - 1997/12/1

Y1 - 1997/12/1

N2 - Chlorosulfonic acid catalyzed cyclization reaction of β-monocyclonerolidol and β-monocyclofarnesol and corresponding acetates gave a unique rearranged product (2S*, 3S*, 4aR*, 8aS*)-1, 3, 4, 5, 6, 7, 8, 8a-octahydro-2, 5, 5, 8a-tetramethyl-2H-2, 4a-methanonaphthalen-3-ol, the structure of which was elucidated by X-ray analysis.

AB - Chlorosulfonic acid catalyzed cyclization reaction of β-monocyclonerolidol and β-monocyclofarnesol and corresponding acetates gave a unique rearranged product (2S*, 3S*, 4aR*, 8aS*)-1, 3, 4, 5, 6, 7, 8, 8a-octahydro-2, 5, 5, 8a-tetramethyl-2H-2, 4a-methanonaphthalen-3-ol, the structure of which was elucidated by X-ray analysis.

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EP - 122

JO - Synlett

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