Stable isotopic and mineralogical studies of hydrothermal alteration at Arima Spa, Southwest Japan

Harue Masuda, Hitoshi Sakai, Hitoshi Chiba, Yukihiro Matsuhisa, Takeshi Nakamura

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)


The waters of Arima Spa, Southwest Japan, have high salinity (Cl = 54 g/kg) and high isotopic ratios (δD = - 32, and δ18O = + 10%.), and issue from shallow wells drilled into altered rhyolitic pyroclastic rocks of Cretaceous age. Alteration of the host rocks occurred in two stages. The earlier regional alteration stage is characterized by the presence of 2M- and IM-type muscovite, albite, chlorite, calcite and epidote, whereas muscovite and Fe-chlorite formation at the expense of partly albitized plagioclase and altered biotite or hornblende occurred in the following hydrothermal stage. Pyrite, sphalerite, galena and siderite are present in the central part of the hydrothermal alteration zone. Oxygen and hydrogen isotopic ratios of secondary muscovite show that regional alteration proceeded under the meteoric circulation, and that the hydrothermal fluid for the second stage had chemical and stable isotopic characteristics of non-meteoric origin similar to the present-day Arima brine. The oxygen and to a lesser extent the hydrogen isotopic ratios of the muscovite rapidly decrease with increasing distance from the central zone of hydrothermal alteration. The isotopic variation is best interpreted as reflecting rapidly decreasing fluid/rock ratios with increasing distance of fluid penetration from the narrow hydrothermal alteration zone into the surrounding area. Speciation computation for the present-day brines at Arima Spa indicates that they are saturated with siderite but not with calcite at depth, in good accord with the mineralogical observations. Upon ascent the brines are diluted by HCO3-rich shallow ground water and are saturated with respect to both siderite and calcite. The present-day Arima hydrothermal system is a remnant of the second stage hydrothermal activity.

Original languageEnglish
Pages (from-to)19-28
Number of pages10
JournalGeochimica et Cosmochimica Acta
Issue number1
Publication statusPublished - Jan 1986

ASJC Scopus subject areas

  • Geochemistry and Petrology


Dive into the research topics of 'Stable isotopic and mineralogical studies of hydrothermal alteration at Arima Spa, Southwest Japan'. Together they form a unique fingerprint.

Cite this