Stable antiaromatic 1,4-diazapentalenes

synthesis and oxidation reaction of 2-vinyl- and 2,5-divinyl-1,4-dihydropyrrolo[3,2-b]pyrrole derivatives

Kyosuke Satake, Daizo Nakogc, Masaru Kimura

Research output: Contribution to journal › Article

6 Citations (Scopus)

Abstract

Stable and isolable 8:1 electrons antiaromatic compounds, 2-vinyl and 2,5-divinyl substituted 1,4-diazapentalenes were synthesized via an oxidation reaction of correspondingly substituted 1,4-dihydro-3,6-di-tert-butylpyrrolo[3,2-b]pyrroles which were prepared by an electrophilic addtion reaction of dimethyl acetylenedicarboxylate (DMAD).

Original languageEnglish
Pages (from-to)433-436
Number of pages4
JournalHeterocycles
Volume48
Issue number3
Publication statusPublished - 1998

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Vinyl Compounds
Pyrroles
Intermetallics
Electrons
Derivatives
Oxidation
dihydropyrrolo(3,2-b)pyrrole
acetylenedicarboxylic acid dimethyl ester
1,3-butadiene

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Stable antiaromatic 1,4-diazapentalenes : synthesis and oxidation reaction of 2-vinyl- and 2,5-divinyl-1,4-dihydropyrrolo[3,2-b]pyrrole derivatives. / Satake, Kyosuke; Nakogc, Daizo; Kimura, Masaru.

In: Heterocycles, Vol. 48, No. 3, 1998, p. 433-436.

Research output: Contribution to journal › Article

Satake, K, Nakogc, D & Kimura, M 1998, 'Stable antiaromatic 1,4-diazapentalenes: synthesis and oxidation reaction of 2-vinyl- and 2,5-divinyl-1,4-dihydropyrrolo[3,2-b]pyrrole derivatives', Heterocycles, vol. 48, no. 3, pp. 433-436.
Satake K, Nakogc D, Kimura M. Stable antiaromatic 1,4-diazapentalenes: synthesis and oxidation reaction of 2-vinyl- and 2,5-divinyl-1,4-dihydropyrrolo[3,2-b]pyrrole derivatives. Heterocycles. 1998;48(3):433-436.
Satake, Kyosuke ; Nakogc, Daizo ; Kimura, Masaru. / Stable antiaromatic 1,4-diazapentalenes : synthesis and oxidation reaction of 2-vinyl- and 2,5-divinyl-1,4-dihydropyrrolo[3,2-b]pyrrole derivatives. In: Heterocycles. 1998 ; Vol. 48, No. 3. pp. 433-436.
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