Stable antiaromatic 1,4-diazapentalenes: synthesis and oxidation reaction of 2-vinyl- and 2,5-divinyl-1,4-dihydropyrrolo[3,2-b]pyrrole derivatives

Kyosukc Satake, Daizo Nakogc, Masaru Kimura

    Research output: Contribution to journalArticlepeer-review

    7 Citations (Scopus)

    Abstract

    Stable and isolable 8:1 electrons antiaromatic compounds, 2-vinyl and 2,5-divinyl substituted 1,4-diazapentalenes were synthesized via an oxidation reaction of correspondingly substituted 1,4-dihydro-3,6-di-tert-butylpyrrolo[3,2-b]pyrroles which were prepared by an electrophilic addtion reaction of dimethyl acetylenedicarboxylate (DMAD).

    Original languageEnglish
    Pages (from-to)433-436
    Number of pages4
    JournalHeterocycles
    Volume48
    Issue number3
    DOIs
    Publication statusPublished - Jan 1 1998

    ASJC Scopus subject areas

    • Analytical Chemistry
    • Pharmacology
    • Organic Chemistry

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