Stable antiaromatic 1,4-diazapentalenes: synthesis and oxidation reaction of 2-vinyl- and 2,5-divinyl-1,4-dihydropyrrolo[3,2-b]pyrrole derivatives

Kyosukc Satake, Daizo Nakogc, Masaru Kimura

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Stable and isolable 8:1 electrons antiaromatic compounds, 2-vinyl and 2,5-divinyl substituted 1,4-diazapentalenes were synthesized via an oxidation reaction of correspondingly substituted 1,4-dihydro-3,6-di-tert-butylpyrrolo[3,2-b]pyrroles which were prepared by an electrophilic addtion reaction of dimethyl acetylenedicarboxylate (DMAD).

Original languageEnglish
Pages (from-to)433-436
Number of pages4
JournalHeterocycles
Volume48
Issue number3
DOIs
Publication statusPublished - Jan 1 1998

ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

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