Spin trapping chemistry of the diphenylphosphinyl radical

Y. Sueishi; Y. Nishihara

doi:10.3184/030823401103169054

Spin trapping chemistry of the diphenylphosphinyl radical

Y. Sueishi, Y. Nishihara

Research output: Contribution to journal › Article

5 Citations (Scopus)

Abstract

The diphenylphosphinyl radical (.PPh₂), produced from hydrogen atom abstraction of diphenylphosphine by 2,2diphenyl-1-picryl-hydrazyl, was trapped by several kinds of spin trap and the relative reactivities of the .PPh₂ radical toward the five kinds of spin trap were determined by competitive reactions using DMPO as a reference.

Original language	English
Pages (from-to)	84-86
Number of pages	3
Journal	Journal of Chemical Research - Part S
Issue number	2
DOIs	https://doi.org/10.3184/030823401103169054
Publication status	Published - Jan 1 2001

Keywords

Diphenylphosphinyl radical
Spin trapping

ASJC Scopus subject areas

Chemistry(all)

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10.3184/030823401103169054

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Sueishi, Y., & Nishihara, Y. (2001). Spin trapping chemistry of the diphenylphosphinyl radical. Journal of Chemical Research - Part S, (2), 84-86. https://doi.org/10.3184/030823401103169054

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abstract = "The diphenylphosphinyl radical (.PPh2), produced from hydrogen atom abstraction of diphenylphosphine by 2,2diphenyl-1-picryl-hydrazyl, was trapped by several kinds of spin trap and the relative reactivities of the .PPh2 radical toward the five kinds of spin trap were determined by competitive reactions using DMPO as a reference.",

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