Spectroscopic Determination of the Site in MFI Zeolite where Cobalt(I) Performs Two-Electron Reduction of O2 at Room Temperature

Akira Oda, Yuki Mamenari, Takahiro Ohkubo, Yasushige Kuroda

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8 Citations (Scopus)


Zeolites have well-defined pores of molecular dimensions to stabilize the molecularly dispersed reactive oxygen species (ROS) responsible for actual key intermediates in a variety of desirable catalytic transformation processes. Defining the local environment to create such an important class of ROS is undoubtedly important for designing more efficient zeolite-based catalysts; however, it remains challenging due to the obscure distribution of the framework Al atoms. In the present study, we defined the local environment of MFI zeolite to create a novel O2 activation property of the cobalt ion. We found that the CoIII-peroxo species is formed through two-electron reduction of O2 at room temperature by an extra lattice CoI species that corresponds to an abnormal oxidation state of Co. This is the first example of the experimental detection of the O2-derived mononuclear metal-peroxo species in zeolites. The change in the skeletal vibrational mode associated with the Al site, νAl-O-Si, upon the O2 activation process was experimentally observed. It provides the information about the position of the framework Al atom. By applying B3LYP-D3 density functional theory (DFT) calculations, we demonstrated that the positioning of the framework Al atom at an interface between straight and sinusoidal channels of MFI zeolite is essential for the formation of the CoIII-peroxo species. The experimentally calibrated DFT model features the S = 1 square planar CoIII-peroxo species bound to the interface region by two anionic lattice oxygen atoms. The CoIII-peroxo species is stabilized only by weak donor O ligands, never previously identified. This unique state is demonstrated by combined experimental and computational analyses of the vibronic progression found for the first time in this system, which provides detailed information about the site geometry and electronic structure. The findings of the present study assist us to understand how the zeolite lattice creates the abnormal O2 activation property of metal ions.

Original languageEnglish
Pages (from-to)17842-17854
Number of pages13
JournalJournal of Physical Chemistry C
Issue number29
Publication statusPublished - Jul 25 2019

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films


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