Spectral reflectance (0.35–2.5 µm) properties of garnets: Implications for remote sensing detection and characterization

Matthew Richar Izawa, E. A. Cloutis, T. Rhind, S. A. Mertzman, Jordan Poitras, Daniel M. Applin, P. Mann

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The utility of spectral reflectance for identification of the main end-member garnets: almandine (Fe2+ 3Al2Si3O12), andradite (Ca3Fe3+ 2Si3O12), grossular (Ca3Al2Si3O12), pyrope (Mg3Al2Si3O12), spessartine (Mn2+ 3Al2Si3O12), and uvarovite (Ca3Cr3+ 2Si3O12) was studied using a suite of 60 garnet samples. Compositional and structural data for the samples, along with previous studies, were used to elucidate the mechanisms that control their spectral reflectance properties. Various cation substitutions result in different spectral properties that can be determine the presence of various optically-active cations and help differentiate between garnet types. It was found that different wavelength regions are sensitive to different compositional and structural properties of garnets. Crystal-field absorptions involving Fe2+ and/or Fe3+ are responsible for the majority of spectral features in the garnet minerals examined here. There can also be spectral features associated with other cations and mechanisms, such as Fe2 +–Fe3+ and Fe2 +–Ti4+ intervalence charge transfers. The visible wavelength region is useful for identifying the presence of various cations, in particular, Fe (and its oxidation state), Ti4+, Mn2+, and Cr3+. In the case of andradite, spessartine and uvarovite, the visible region absorption bands are characteristic of these garnets in the sense that they are associated with the major cation that distinguishes each: [6]Fe3+ for andradite, [8]Mn2+ for spessartine, and [6]Cr3+ for uvarovite. For grossular, the presence of small amounts of Fe3+ leads to absorption bands near 0.370 and 0.435 µm. These bands are also seen in pyrope–almandine spectra, which also commonly have additional absorption bands, due to the presence of Fe2+. The common presence of Fe2+ in the dodecahedral site of natural garnets gives rise to three Fe2+ spin-allowed absorption bands in the 1.3, 1.7, and 2.3 µm regions, providing a strong spectral fingerprint for all Fe2+-bearing garnets studied here. Garnets containing Mn2+ have additional visible (∼0.41 µm) spectral features due to [8]Mn2+. Garnets containing Cr3+, exhibits two strong absorption bands near ∼0.7 µm due to spin-forbidden [6]Cr3+ transitions, as well as [6]Cr3+ spin-allowed features near 0.4–0.41 µm and 0.56–0.62 µm, and [6]Cr3+ spin-allowed transitions between 0.41 and 0.68 µm. Common silicate garnet spectra, in summary, are distinct from many other rock-forming silicates and can be spectrally distinct from one garnet species to another. Iron dominates the spectral properties of garnets, and the crystallographic site and oxidation state of the iron both affect garnet reflectance spectra.

Original languageEnglish
Pages (from-to)392-410
Number of pages19
JournalIcarus
Volume300
DOIs
Publication statusPublished - Jan 15 2018

Fingerprint

spectral reflectance
garnets
remote sensing
garnet
spessartine
andradite
cation
absorption spectra
cations
grossular
detection
silicates
silicate
wavelength
iron
oxidation
almandine
pyrope
wavelengths
crystal field theory

Keywords

  • Garnet
  • Reflectance spectroscopy
  • Remote sensing

ASJC Scopus subject areas

  • Astronomy and Astrophysics
  • Space and Planetary Science

Cite this

Spectral reflectance (0.35–2.5 µm) properties of garnets : Implications for remote sensing detection and characterization. / Richar Izawa, Matthew; Cloutis, E. A.; Rhind, T.; Mertzman, S. A.; Poitras, Jordan; Applin, Daniel M.; Mann, P.

In: Icarus, Vol. 300, 15.01.2018, p. 392-410.

Research output: Contribution to journalArticle

Richar Izawa, Matthew ; Cloutis, E. A. ; Rhind, T. ; Mertzman, S. A. ; Poitras, Jordan ; Applin, Daniel M. ; Mann, P. / Spectral reflectance (0.35–2.5 µm) properties of garnets : Implications for remote sensing detection and characterization. In: Icarus. 2018 ; Vol. 300. pp. 392-410.
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abstract = "The utility of spectral reflectance for identification of the main end-member garnets: almandine (Fe2+ 3Al2Si3O12), andradite (Ca3Fe3+ 2Si3O12), grossular (Ca3Al2Si3O12), pyrope (Mg3Al2Si3O12), spessartine (Mn2+ 3Al2Si3O12), and uvarovite (Ca3Cr3+ 2Si3O12) was studied using a suite of 60 garnet samples. Compositional and structural data for the samples, along with previous studies, were used to elucidate the mechanisms that control their spectral reflectance properties. Various cation substitutions result in different spectral properties that can be determine the presence of various optically-active cations and help differentiate between garnet types. It was found that different wavelength regions are sensitive to different compositional and structural properties of garnets. Crystal-field absorptions involving Fe2+ and/or Fe3+ are responsible for the majority of spectral features in the garnet minerals examined here. There can also be spectral features associated with other cations and mechanisms, such as Fe2 +–Fe3+ and Fe2 +–Ti4+ intervalence charge transfers. The visible wavelength region is useful for identifying the presence of various cations, in particular, Fe (and its oxidation state), Ti4+, Mn2+, and Cr3+. In the case of andradite, spessartine and uvarovite, the visible region absorption bands are characteristic of these garnets in the sense that they are associated with the major cation that distinguishes each: [6]Fe3+ for andradite, [8]Mn2+ for spessartine, and [6]Cr3+ for uvarovite. For grossular, the presence of small amounts of Fe3+ leads to absorption bands near 0.370 and 0.435 µm. These bands are also seen in pyrope–almandine spectra, which also commonly have additional absorption bands, due to the presence of Fe2+. The common presence of Fe2+ in the dodecahedral site of natural garnets gives rise to three Fe2+ spin-allowed absorption bands in the 1.3, 1.7, and 2.3 µm regions, providing a strong spectral fingerprint for all Fe2+-bearing garnets studied here. Garnets containing Mn2+ have additional visible (∼0.41 µm) spectral features due to [8]Mn2+. Garnets containing Cr3+, exhibits two strong absorption bands near ∼0.7 µm due to spin-forbidden [6]Cr3+ transitions, as well as [6]Cr3+ spin-allowed features near 0.4–0.41 µm and 0.56–0.62 µm, and [6]Cr3+ spin-allowed transitions between 0.41 and 0.68 µm. Common silicate garnet spectra, in summary, are distinct from many other rock-forming silicates and can be spectrally distinct from one garnet species to another. Iron dominates the spectral properties of garnets, and the crystallographic site and oxidation state of the iron both affect garnet reflectance spectra.",
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T1 - Spectral reflectance (0.35–2.5 µm) properties of garnets

T2 - Implications for remote sensing detection and characterization

AU - Richar Izawa, Matthew

AU - Cloutis, E. A.

AU - Rhind, T.

AU - Mertzman, S. A.

AU - Poitras, Jordan

AU - Applin, Daniel M.

AU - Mann, P.

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N2 - The utility of spectral reflectance for identification of the main end-member garnets: almandine (Fe2+ 3Al2Si3O12), andradite (Ca3Fe3+ 2Si3O12), grossular (Ca3Al2Si3O12), pyrope (Mg3Al2Si3O12), spessartine (Mn2+ 3Al2Si3O12), and uvarovite (Ca3Cr3+ 2Si3O12) was studied using a suite of 60 garnet samples. Compositional and structural data for the samples, along with previous studies, were used to elucidate the mechanisms that control their spectral reflectance properties. Various cation substitutions result in different spectral properties that can be determine the presence of various optically-active cations and help differentiate between garnet types. It was found that different wavelength regions are sensitive to different compositional and structural properties of garnets. Crystal-field absorptions involving Fe2+ and/or Fe3+ are responsible for the majority of spectral features in the garnet minerals examined here. There can also be spectral features associated with other cations and mechanisms, such as Fe2 +–Fe3+ and Fe2 +–Ti4+ intervalence charge transfers. The visible wavelength region is useful for identifying the presence of various cations, in particular, Fe (and its oxidation state), Ti4+, Mn2+, and Cr3+. In the case of andradite, spessartine and uvarovite, the visible region absorption bands are characteristic of these garnets in the sense that they are associated with the major cation that distinguishes each: [6]Fe3+ for andradite, [8]Mn2+ for spessartine, and [6]Cr3+ for uvarovite. For grossular, the presence of small amounts of Fe3+ leads to absorption bands near 0.370 and 0.435 µm. These bands are also seen in pyrope–almandine spectra, which also commonly have additional absorption bands, due to the presence of Fe2+. The common presence of Fe2+ in the dodecahedral site of natural garnets gives rise to three Fe2+ spin-allowed absorption bands in the 1.3, 1.7, and 2.3 µm regions, providing a strong spectral fingerprint for all Fe2+-bearing garnets studied here. Garnets containing Mn2+ have additional visible (∼0.41 µm) spectral features due to [8]Mn2+. Garnets containing Cr3+, exhibits two strong absorption bands near ∼0.7 µm due to spin-forbidden [6]Cr3+ transitions, as well as [6]Cr3+ spin-allowed features near 0.4–0.41 µm and 0.56–0.62 µm, and [6]Cr3+ spin-allowed transitions between 0.41 and 0.68 µm. Common silicate garnet spectra, in summary, are distinct from many other rock-forming silicates and can be spectrally distinct from one garnet species to another. Iron dominates the spectral properties of garnets, and the crystallographic site and oxidation state of the iron both affect garnet reflectance spectra.

AB - The utility of spectral reflectance for identification of the main end-member garnets: almandine (Fe2+ 3Al2Si3O12), andradite (Ca3Fe3+ 2Si3O12), grossular (Ca3Al2Si3O12), pyrope (Mg3Al2Si3O12), spessartine (Mn2+ 3Al2Si3O12), and uvarovite (Ca3Cr3+ 2Si3O12) was studied using a suite of 60 garnet samples. Compositional and structural data for the samples, along with previous studies, were used to elucidate the mechanisms that control their spectral reflectance properties. Various cation substitutions result in different spectral properties that can be determine the presence of various optically-active cations and help differentiate between garnet types. It was found that different wavelength regions are sensitive to different compositional and structural properties of garnets. Crystal-field absorptions involving Fe2+ and/or Fe3+ are responsible for the majority of spectral features in the garnet minerals examined here. There can also be spectral features associated with other cations and mechanisms, such as Fe2 +–Fe3+ and Fe2 +–Ti4+ intervalence charge transfers. The visible wavelength region is useful for identifying the presence of various cations, in particular, Fe (and its oxidation state), Ti4+, Mn2+, and Cr3+. In the case of andradite, spessartine and uvarovite, the visible region absorption bands are characteristic of these garnets in the sense that they are associated with the major cation that distinguishes each: [6]Fe3+ for andradite, [8]Mn2+ for spessartine, and [6]Cr3+ for uvarovite. For grossular, the presence of small amounts of Fe3+ leads to absorption bands near 0.370 and 0.435 µm. These bands are also seen in pyrope–almandine spectra, which also commonly have additional absorption bands, due to the presence of Fe2+. The common presence of Fe2+ in the dodecahedral site of natural garnets gives rise to three Fe2+ spin-allowed absorption bands in the 1.3, 1.7, and 2.3 µm regions, providing a strong spectral fingerprint for all Fe2+-bearing garnets studied here. Garnets containing Mn2+ have additional visible (∼0.41 µm) spectral features due to [8]Mn2+. Garnets containing Cr3+, exhibits two strong absorption bands near ∼0.7 µm due to spin-forbidden [6]Cr3+ transitions, as well as [6]Cr3+ spin-allowed features near 0.4–0.41 µm and 0.56–0.62 µm, and [6]Cr3+ spin-allowed transitions between 0.41 and 0.68 µm. Common silicate garnet spectra, in summary, are distinct from many other rock-forming silicates and can be spectrally distinct from one garnet species to another. Iron dominates the spectral properties of garnets, and the crystallographic site and oxidation state of the iron both affect garnet reflectance spectra.

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