Solvation forces and liquid-solid phase equilibria for water confined between hydrophobic surfaces

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

Molecular dynamics simulation model was used to study solvation forces and liquid-solid phase equilibria of water confined between hydrophobic surfaces. The thermodynamics for a confined system at constant surface separation, temperature and lateral or bulk pressure were analyzed. Freezing and melting of water at certain intersurface separations were observed. The solvation force curves exhibited discontinuous changes and large hysteresis due to the phase transitions.

Original languageEnglish
Pages (from-to)10882-10889
Number of pages8
JournalThe Journal of Chemical Physics
Volume116
Issue number24
DOIs
Publication statusPublished - Jun 22 2002
Externally publishedYes

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Solvation
Phase equilibria
solvation
solid phases
Water
Liquids
liquids
Freezing
freezing
water
Hysteresis
Molecular dynamics
Melting
Phase transitions
hysteresis
melting
Thermodynamics
molecular dynamics
thermodynamics
Computer simulation

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Solvation forces and liquid-solid phase equilibria for water confined between hydrophobic surfaces. / Koga, Kenichiro.

In: The Journal of Chemical Physics, Vol. 116, No. 24, 22.06.2002, p. 10882-10889.

Research output: Contribution to journalArticle

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