Abstract
Molecular dynamics simulation model was used to study solvation forces and liquid-solid phase equilibria of water confined between hydrophobic surfaces. The thermodynamics for a confined system at constant surface separation, temperature and lateral or bulk pressure were analyzed. Freezing and melting of water at certain intersurface separations were observed. The solvation force curves exhibited discontinuous changes and large hysteresis due to the phase transitions.
| Original language | English |
|---|---|
| Pages (from-to) | 10882-10889 |
| Number of pages | 8 |
| Journal | The Journal of Chemical Physics |
| Volume | 116 |
| Issue number | 24 |
| DOIs | |
| Publication status | Published - Jun 22 2002 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
Cite this
Solvation forces and liquid-solid phase equilibria for water confined between hydrophobic surfaces. / Koga, Kenichiro.
In: The Journal of Chemical Physics, Vol. 116, No. 24, 22.06.2002, p. 10882-10889.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Solvation forces and liquid-solid phase equilibria for water confined between hydrophobic surfaces
AU - Koga, Kenichiro
PY - 2002/6/22
Y1 - 2002/6/22
N2 - Molecular dynamics simulation model was used to study solvation forces and liquid-solid phase equilibria of water confined between hydrophobic surfaces. The thermodynamics for a confined system at constant surface separation, temperature and lateral or bulk pressure were analyzed. Freezing and melting of water at certain intersurface separations were observed. The solvation force curves exhibited discontinuous changes and large hysteresis due to the phase transitions.
AB - Molecular dynamics simulation model was used to study solvation forces and liquid-solid phase equilibria of water confined between hydrophobic surfaces. The thermodynamics for a confined system at constant surface separation, temperature and lateral or bulk pressure were analyzed. Freezing and melting of water at certain intersurface separations were observed. The solvation force curves exhibited discontinuous changes and large hysteresis due to the phase transitions.
UR - http://www.scopus.com/inward/record.url?scp=0037157641&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0037157641&partnerID=8YFLogxK
U2 - 10.1063/1.1480855
DO - 10.1063/1.1480855
M3 - Article
AN - SCOPUS:0037157641
VL - 116
SP - 10882
EP - 10889
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
SN - 0021-9606
IS - 24
ER -