Solid state NMR characterization of nano-crystalline hydroxy-carbonate apatite using 1H-31P-13C triple resonance experiments

Florence Babonneau, Christian Bonhomme, Satoshi Hayakawa, Akiyoshi Osaka

Research output: Chapter in Book/Report/Conference proceedingConference contribution

6 Citations (Scopus)

Abstract

The local structure around hydrogen atoms, phosphate ions and carbonate ions in nano-crystalline nonstoichiometric hydroxy-carbonate apatite was investigated in this study. The use of C enriched precursors allowed to perform 1D and 2D CP MAS HETCOR (HETeronuclear CORrelation) experiments with 13C as a target spin. 2D triple resonance experiments involving the 1H/13C/31P spins were also performed. All these experiments led to the partial editing of the corresponding projection spectra and revealed fine structural details for the corresponding material. At least four 13C peaks, corresponding to carbonate ions in A-sites (OH) and B-sites (PO43-) were evidenced.

Original languageEnglish
Title of host publicationMaterials Research Society Symposium Proceedings
Pages39-44
Number of pages6
Volume984
Publication statusPublished - 2007
Event2006 MRS Fall Meeting - Boston, MA, United States
Duration: Nov 27 2006Dec 1 2006

Other

Other2006 MRS Fall Meeting
CountryUnited States
CityBoston, MA
Period11/27/0612/1/06

Fingerprint

Apatite
Carbonates
Nuclear magnetic resonance
Ions
Crystalline materials
Experiments
Hydrogen
Phosphates
Atoms
carboapatite

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials

Cite this

Babonneau, F., Bonhomme, C., Hayakawa, S., & Osaka, A. (2007). Solid state NMR characterization of nano-crystalline hydroxy-carbonate apatite using 1H-31P-13C triple resonance experiments. In Materials Research Society Symposium Proceedings (Vol. 984, pp. 39-44)

Solid state NMR characterization of nano-crystalline hydroxy-carbonate apatite using 1H-31P-13C triple resonance experiments. / Babonneau, Florence; Bonhomme, Christian; Hayakawa, Satoshi; Osaka, Akiyoshi.

Materials Research Society Symposium Proceedings. Vol. 984 2007. p. 39-44.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Babonneau, F, Bonhomme, C, Hayakawa, S & Osaka, A 2007, Solid state NMR characterization of nano-crystalline hydroxy-carbonate apatite using 1H-31P-13C triple resonance experiments. in Materials Research Society Symposium Proceedings. vol. 984, pp. 39-44, 2006 MRS Fall Meeting, Boston, MA, United States, 11/27/06.
Babonneau F, Bonhomme C, Hayakawa S, Osaka A. Solid state NMR characterization of nano-crystalline hydroxy-carbonate apatite using 1H-31P-13C triple resonance experiments. In Materials Research Society Symposium Proceedings. Vol. 984. 2007. p. 39-44
Babonneau, Florence ; Bonhomme, Christian ; Hayakawa, Satoshi ; Osaka, Akiyoshi. / Solid state NMR characterization of nano-crystalline hydroxy-carbonate apatite using 1H-31P-13C triple resonance experiments. Materials Research Society Symposium Proceedings. Vol. 984 2007. pp. 39-44
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