Site-selective introduction of an enamido group at the C(3)-Position of Indoles

Tomoya Miura, Qiang Zhao, Yuuta Funakoshi, Masahiro Murakami

Research output: Contribution to journalArticlepeer-review

14 Citations (Scopus)

Abstract

An enamido group is introduced site-selectively at the C(3)-position of indoles by the rhodium(II)-catalyzed reaction with N-sulfonyl-1,2,3-triazoles. Formally, an α-imino rhodium carbene complex is inserted into the C(3)-H bond of an indole.

Original languageEnglish
Pages (from-to)1579-1584
Number of pages6
JournalHeterocycles
Volume91
Issue number8
DOIs
Publication statusPublished - 2015
Externally publishedYes

ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

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