Single electrode heat of molten NaCl electrolysis: measurement by electrolytic calorimeter and heat flux transducer (HFT)

Yasuhiko Ito; Hidetaka Hayashi; Norio Hayafuji; Shiro Yoshizawa

doi:10.1007/BF00620562

Single electrode heat of molten NaCl electrolysis: measurement by electrolytic calorimeter and heat flux transducer (HFT)

Yasuhiko Ito, Hidetaka Hayashi, Norio Hayafuji, Shiro Yoshizawa

Graduate School of Natural Science and Technology

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

An electrolytic calorimeter employing a heat flux transducer (HFT) has been developed. By means of this apparatus the single electrode Peltier heat for the anodic chlorine evolution reaction in the electrolysis of molten NaCl-ZnCl₂ using a β-alumina diaphragm was measured. The value of the single electrode Peltier heat obtained by such a method was 0.697 J C^-1 at 377° C, which is very close to the value 0.614 J C^-1 previously determined by a thermoelectric power measurement. The coincidence between the two methods indicates that a thermoelectric power measurement is quite valid for determining the single electrode Peltier heat.

Original language	English
Pages (from-to)	671-674
Number of pages	4
Journal	Journal of Applied Electrochemistry
Volume	15
Issue number	5
DOIs	https://doi.org/10.1007/BF00620562
Publication status	Published - Sept 1 1985

ASJC Scopus subject areas

Chemical Engineering(all)
Electrochemistry
Materials Chemistry

Access to Document

10.1007/BF00620562

Cite this

@article{1074f2ff41ad40449bf9e8fe5ec1c876,

title = "Single electrode heat of molten NaCl electrolysis: measurement by electrolytic calorimeter and heat flux transducer (HFT)",

abstract = "An electrolytic calorimeter employing a heat flux transducer (HFT) has been developed. By means of this apparatus the single electrode Peltier heat for the anodic chlorine evolution reaction in the electrolysis of molten NaCl-ZnCl2 using a β-alumina diaphragm was measured. The value of the single electrode Peltier heat obtained by such a method was 0.697 J C-1 at 377° C, which is very close to the value 0.614 J C-1 previously determined by a thermoelectric power measurement. The coincidence between the two methods indicates that a thermoelectric power measurement is quite valid for determining the single electrode Peltier heat.",

author = "Yasuhiko Ito and Hidetaka Hayashi and Norio Hayafuji and Shiro Yoshizawa",

year = "1985",

month = sep,

day = "1",

doi = "10.1007/BF00620562",

language = "English",

volume = "15",

pages = "671--674",

journal = "Journal of Applied Electrochemistry",

issn = "0021-891X",

publisher = "Springer Netherlands",

number = "5",

}

TY - JOUR

T1 - Single electrode heat of molten NaCl electrolysis

T2 - measurement by electrolytic calorimeter and heat flux transducer (HFT)

AU - Ito, Yasuhiko

AU - Hayashi, Hidetaka

AU - Hayafuji, Norio

AU - Yoshizawa, Shiro

PY - 1985/9/1

Y1 - 1985/9/1

N2 - An electrolytic calorimeter employing a heat flux transducer (HFT) has been developed. By means of this apparatus the single electrode Peltier heat for the anodic chlorine evolution reaction in the electrolysis of molten NaCl-ZnCl2 using a β-alumina diaphragm was measured. The value of the single electrode Peltier heat obtained by such a method was 0.697 J C-1 at 377° C, which is very close to the value 0.614 J C-1 previously determined by a thermoelectric power measurement. The coincidence between the two methods indicates that a thermoelectric power measurement is quite valid for determining the single electrode Peltier heat.

AB - An electrolytic calorimeter employing a heat flux transducer (HFT) has been developed. By means of this apparatus the single electrode Peltier heat for the anodic chlorine evolution reaction in the electrolysis of molten NaCl-ZnCl2 using a β-alumina diaphragm was measured. The value of the single electrode Peltier heat obtained by such a method was 0.697 J C-1 at 377° C, which is very close to the value 0.614 J C-1 previously determined by a thermoelectric power measurement. The coincidence between the two methods indicates that a thermoelectric power measurement is quite valid for determining the single electrode Peltier heat.

UR - http://www.scopus.com/inward/record.url?scp=0022131426&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0022131426&partnerID=8YFLogxK

U2 - 10.1007/BF00620562

DO - 10.1007/BF00620562

M3 - Article

AN - SCOPUS:0022131426

SN - 0021-891X

VL - 15

SP - 671

EP - 674

JO - Journal of Applied Electrochemistry

JF - Journal of Applied Electrochemistry

IS - 5

ER -

Single electrode heat of molten NaCl electrolysis: measurement by electrolytic calorimeter and heat flux transducer (HFT)

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this