Single crystal X-ray study of pressure-induced metal-insulator transition in (DMeDCNQI)2Cu

Y. Nogami, T. Date, K. Oshima, O. Arimoto

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The structures of the metallic and the insulating phases of (DMeDCNQI)2Cu were solved under pressures of up to 15.8 kbar at room temperature. An angle α representing the deformation of CuN4 tetrahedron around the Cu atom increases almost linearly with pressure at the rate of about 0.6 deg./ kbar. Furthermore, an X-ray diffuse scattering study revealed the presence of a 3 c CDW superlattice structure above 12 kbar in the high pressure insulating phase.

Original languageEnglish
Pages (from-to)2073-2074
Number of pages2
JournalSynthetic Metals
Volume86
Issue number1-3
DOIs
Publication statusPublished - Feb 28 1997

Keywords

  • Diffraction and scattering
  • Organic semiconductors based on conjugated molecules
  • Structural phase transition
  • X-ray emission

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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