Abstract
5-Hydroxymethylfurfural (HMF) was obtained from the dehydration of fructose under high temperature and pressure conditions (180 °C and 10 MPa). To avoid the decomposition of HMF in the bulk aqueous phase, we dehydrated fructose in the water / metyl isobuthyl ketone (MIBK) biphasic system. The HMF could be successfully extracted into the organic MIBK phase without further decomposition of HMF. We present a simplified model taking into consideration of the slug flow with the wall film to maximize the HMF yield in the MIBK phase. It was likely that the slug flow contributed to an increase in the surface-to-volume ratio for the mass transfer of HMF.
| Original language | English |
|---|---|
| Pages (from-to) | 205-212 |
| Number of pages | 8 |
| Journal | Solvent Extraction Research and Development |
| Volume | 20 |
| Publication status | Published - 2013 |
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ASJC Scopus subject areas
- Chemistry(all)
- Chemical Engineering(all)
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Simplified model for extraction of 5-hydroxymethylfurfural from fructose : Use of water/oil biphasic system under high temperature and pressure conditions. / Shimanouchi, Toshinori; Kataoka, Yoshitaka; Yasukawa, Masahiro; Ono, Tsutomu; Kimura, Yukitaka.
In: Solvent Extraction Research and Development, Vol. 20, 2013, p. 205-212.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Simplified model for extraction of 5-hydroxymethylfurfural from fructose
T2 - Use of water/oil biphasic system under high temperature and pressure conditions
AU - Shimanouchi, Toshinori
AU - Kataoka, Yoshitaka
AU - Yasukawa, Masahiro
AU - Ono, Tsutomu
AU - Kimura, Yukitaka
PY - 2013
Y1 - 2013
N2 - 5-Hydroxymethylfurfural (HMF) was obtained from the dehydration of fructose under high temperature and pressure conditions (180 °C and 10 MPa). To avoid the decomposition of HMF in the bulk aqueous phase, we dehydrated fructose in the water / metyl isobuthyl ketone (MIBK) biphasic system. The HMF could be successfully extracted into the organic MIBK phase without further decomposition of HMF. We present a simplified model taking into consideration of the slug flow with the wall film to maximize the HMF yield in the MIBK phase. It was likely that the slug flow contributed to an increase in the surface-to-volume ratio for the mass transfer of HMF.
AB - 5-Hydroxymethylfurfural (HMF) was obtained from the dehydration of fructose under high temperature and pressure conditions (180 °C and 10 MPa). To avoid the decomposition of HMF in the bulk aqueous phase, we dehydrated fructose in the water / metyl isobuthyl ketone (MIBK) biphasic system. The HMF could be successfully extracted into the organic MIBK phase without further decomposition of HMF. We present a simplified model taking into consideration of the slug flow with the wall film to maximize the HMF yield in the MIBK phase. It was likely that the slug flow contributed to an increase in the surface-to-volume ratio for the mass transfer of HMF.
UR - http://www.scopus.com/inward/record.url?scp=84879226936&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84879226936&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:84879226936
VL - 20
SP - 205
EP - 212
JO - Solvent Extraction Research and Development
JF - Solvent Extraction Research and Development
SN - 1341-7215
ER -