Sila-sonogashira cross-coupling reactions of activated aryl chlorides with alkynylsilanes

Yasushi Nishihara, Eiji Inoue, Yoshiaki Okada, Kentaro Takagi

    Research output: Contribution to journalArticlepeer-review

    35 Citations (Scopus)

    Abstract

    The palladium/copper-cocatalyzed sila-Sonogashira cross-coupling reactions of activated aryl chlorides with alkynyl-silanes under strictly nonbasic conditions yield the unsymmetrical diarylethynes in moderate to good yields.

    Original languageEnglish
    Pages (from-to)3041-3045
    Number of pages5
    JournalSynlett
    Issue number19
    DOIs
    Publication statusPublished - Dec 1 2008

    Keywords

    • Alkynyl-silane
    • Aryl chloride
    • Copper
    • Diarylethynes
    • Palladium
    • Sonogashira reaction

    ASJC Scopus subject areas

    • Organic Chemistry

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