Sila-sonogashira cross-coupling reactions of activated aryl chlorides with alkynylsilanes

Yasushi Nishihara; Eiji Inoue; Yoshiaki Okada; Kentaro Takagi

doi:10.1055/s-0028-1087345

Sila-sonogashira cross-coupling reactions of activated aryl chlorides with alkynylsilanes

Yasushi Nishihara, Eiji Inoue, Yoshiaki Okada, Kentaro Takagi

Research Institute for Interdisciplinary Science

Research output: Contribution to journal › Article › peer-review

32 Citations (Scopus)

Abstract

The palladium/copper-cocatalyzed sila-Sonogashira cross-coupling reactions of activated aryl chlorides with alkynyl-silanes under strictly nonbasic conditions yield the unsymmetrical diarylethynes in moderate to good yields.

Original language	English
Pages (from-to)	3041-3045
Number of pages	5
Journal	Synlett
Issue number	19
DOIs	https://doi.org/10.1055/s-0028-1087345
Publication status	Published - Dec 1 2008

Keywords

Alkynyl-silane
Aryl chloride
Copper
Diarylethynes
Palladium
Sonogashira reaction

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-0028-1087345

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title = "Sila-sonogashira cross-coupling reactions of activated aryl chlorides with alkynylsilanes",

abstract = "The palladium/copper-cocatalyzed sila-Sonogashira cross-coupling reactions of activated aryl chlorides with alkynyl-silanes under strictly nonbasic conditions yield the unsymmetrical diarylethynes in moderate to good yields.",

keywords = "Alkynyl-silane, Aryl chloride, Copper, Diarylethynes, Palladium, Sonogashira reaction",

author = "Yasushi Nishihara and Eiji Inoue and Yoshiaki Okada and Kentaro Takagi",

year = "2008",

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AU - Nishihara, Yasushi

AU - Inoue, Eiji

AU - Okada, Yoshiaki

AU - Takagi, Kentaro

PY - 2008/12/1

Y1 - 2008/12/1

N2 - The palladium/copper-cocatalyzed sila-Sonogashira cross-coupling reactions of activated aryl chlorides with alkynyl-silanes under strictly nonbasic conditions yield the unsymmetrical diarylethynes in moderate to good yields.

AB - The palladium/copper-cocatalyzed sila-Sonogashira cross-coupling reactions of activated aryl chlorides with alkynyl-silanes under strictly nonbasic conditions yield the unsymmetrical diarylethynes in moderate to good yields.

KW - Alkynyl-silane

KW - Aryl chloride

KW - Copper

KW - Diarylethynes

KW - Palladium

KW - Sonogashira reaction

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