Sila-sonogashira cross-coupling reactions of activated aryl chlorides with alkynylsilanes

Yasushi Nishihara, Eiji Inoue, Yoshiaki Okada, Kentaro Takagi

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

The palladium/copper-cocatalyzed sila-Sonogashira cross-coupling reactions of activated aryl chlorides with alkynyl-silanes under strictly nonbasic conditions yield the unsymmetrical diarylethynes in moderate to good yields.

Original languageEnglish
Pages (from-to)3041-3045
Number of pages5
JournalSynlett
Issue number19
DOIs
Publication statusPublished - Dec 1 2008

Keywords

  • Alkynyl-silane
  • Aryl chloride
  • Copper
  • Diarylethynes
  • Palladium
  • Sonogashira reaction

ASJC Scopus subject areas

  • Organic Chemistry

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