Ruthenium(II) complex containing a new hybrid bidentate phosphine-thioether ligand: [(p-cymene)RuCl-(Me2PCH2CH2SMe)][BPh 4].0.5CH2Cl2

Takayoshi Suzuki, Norihiko Taguchi, Kazuo Kashiwabara

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

In the title compound, chloro(η 6-p-cymene)[1-(dimethylphosphino-P)-2-(methylthio-S)ethane] ruthenium(II) tetraphenylborate hemidichloromethane solvate, [RuCl-(C10H14)(C5H13PS)][B(C 6H5)4].0.5CH2Cl2, the hybrid Me2PCH2CH2SMe ligand is bidentate (κ2P,S), forming a five-membered chelate ring. The complex cation has two chiral centres, i.e. on the Ru and S atoms, and the relative configuration is R *(Ru)S*(S).

Original languageEnglish
Pages (from-to)2982-2984
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume52
Issue number12
Publication statusPublished - Dec 15 1996
Externally publishedYes

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phosphine
Tetraphenylborate
Ethane
Ruthenium
Sulfides
chelates
phosphines
ethane
ruthenium
Cations
Ligands
cations
Atoms
ligands
rings
configurations
atoms
4-cymene

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

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title = "Ruthenium(II) complex containing a new hybrid bidentate phosphine-thioether ligand: [(p-cymene)RuCl-(Me2PCH2CH2SMe)][BPh 4].0.5CH2Cl2",
abstract = "In the title compound, chloro(η 6-p-cymene)[1-(dimethylphosphino-P)-2-(methylthio-S)ethane] ruthenium(II) tetraphenylborate hemidichloromethane solvate, [RuCl-(C10H14)(C5H13PS)][B(C 6H5)4].0.5CH2Cl2, the hybrid Me2PCH2CH2SMe ligand is bidentate (κ2P,S), forming a five-membered chelate ring. The complex cation has two chiral centres, i.e. on the Ru and S atoms, and the relative configuration is R *(Ru)S*(S).",
author = "Takayoshi Suzuki and Norihiko Taguchi and Kazuo Kashiwabara",
year = "1996",
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journal = "Acta Crystallographica Section C: Crystal Structure Communications",
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publisher = "International Union of Crystallography",
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TY - JOUR

T1 - Ruthenium(II) complex containing a new hybrid bidentate phosphine-thioether ligand

T2 - [(p-cymene)RuCl-(Me2PCH2CH2SMe)][BPh 4].0.5CH2Cl2

AU - Suzuki, Takayoshi

AU - Taguchi, Norihiko

AU - Kashiwabara, Kazuo

PY - 1996/12/15

Y1 - 1996/12/15

N2 - In the title compound, chloro(η 6-p-cymene)[1-(dimethylphosphino-P)-2-(methylthio-S)ethane] ruthenium(II) tetraphenylborate hemidichloromethane solvate, [RuCl-(C10H14)(C5H13PS)][B(C 6H5)4].0.5CH2Cl2, the hybrid Me2PCH2CH2SMe ligand is bidentate (κ2P,S), forming a five-membered chelate ring. The complex cation has two chiral centres, i.e. on the Ru and S atoms, and the relative configuration is R *(Ru)S*(S).

AB - In the title compound, chloro(η 6-p-cymene)[1-(dimethylphosphino-P)-2-(methylthio-S)ethane] ruthenium(II) tetraphenylborate hemidichloromethane solvate, [RuCl-(C10H14)(C5H13PS)][B(C 6H5)4].0.5CH2Cl2, the hybrid Me2PCH2CH2SMe ligand is bidentate (κ2P,S), forming a five-membered chelate ring. The complex cation has two chiral centres, i.e. on the Ru and S atoms, and the relative configuration is R *(Ru)S*(S).

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