Ruthenium(II) complex containing a new hybrid bidentate phosphine-thioether ligand: [(p-cymene)RuCl-(Me2PCH2CH2SMe)][BPh 4].0.5CH2Cl2

Takayoshi Suzuki, Norihiko Taguchi, Kazuo Kashiwabara

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

In the title compound, chloro(η 6-p-cymene)[1-(dimethylphosphino-P)-2-(methylthio-S)ethane] ruthenium(II) tetraphenylborate hemidichloromethane solvate, [RuCl-(C10H14)(C5H13PS)][B(C 6H5)4].0.5CH2Cl2, the hybrid Me2PCH2CH2SMe ligand is bidentate (κ2P,S), forming a five-membered chelate ring. The complex cation has two chiral centres, i.e. on the Ru and S atoms, and the relative configuration is R *(Ru)S*(S).

Original languageEnglish
Pages (from-to)2982-2984
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume52
Issue number12
DOIs
Publication statusPublished - Dec 15 1996
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

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