Role of Vicinal Diol Controller in Discriminating π(C=C)-Faces of Dipolarophile in Nitrone-Olefin Cycloaddition Reactions

Seiki Saito, Teruhiko Ishikawa, Toshio Moriwake

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

Diastereofaces of carbon-carbon double bonds linked to (4S,5S)-bis(t-butyldimethylsiloxy)-framework as a controller of acyclic conformation have been differentiated with >99 %de in nitrone-olefin [3+2] cycloaddition reactions, whereas the nitrones were discriminated with selectivity ranging from 60 to 88 %de.

Original languageEnglish
Pages (from-to)279-281
Number of pages3
JournalSynlett
Volume1994
Issue number4
DOIs
Publication statusPublished - Apr 1 1994

ASJC Scopus subject areas

  • Organic Chemistry

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