Rhodium-catalyzed carbene-transfer reactions via thienylcarbene complexes generated from thiocarbamoyl-ene-yne compounds

Asuka Tsuneishi, Kazuhiro Okamoto, Yuji Ikeda, Masahito Murai, Koji Miki, Kouichi Ohe

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Catalytic thienylcarbene-transfer reactions have been developed. The rhodium-catalyzed reaction of alkenes, furans, and thiophenes with a thiocarbamoyl-ene-yne compound as a carbene source gave the cyclopropanation products or ring-opened products of heterocycles. These processes provide efficient synthetic methods for thiophene-containing complex molecules.

Original languageEnglish
Article numberU11510ST
Pages (from-to)655-658
Number of pages4
JournalSynlett
Issue number5
DOIs
Publication statusPublished - Feb 14 2011

Keywords

  • carbene complex
  • cyclopropanation
  • rhodium
  • ring-opening reaction
  • thiocarbamoyl-ene-yne

ASJC Scopus subject areas

  • Organic Chemistry

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