Rhodium-catalysed substitutive arylation of cis-allylic diols with arylboroxines

Tomoya Miura, Yusuke Takahashi, Masahiro Murakami

Research output: Contribution to journalArticlepeer-review

53 Citations (Scopus)

Abstract

Substitutive arylation of cis-allylic diols occurs upon treatment with arylboroxines in the presence of a rhodium(i) catalyst; the reaction proceeds through the addition of an intermediate arylrhodium(i) species across the carbon-carbon double bond and subsequent β-oxygen elimination.

Original languageEnglish
Pages (from-to)595-597
Number of pages3
JournalChemical Communications
Issue number6
DOIs
Publication statusPublished - 2007
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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