Rhenium-catalyzed ortho-alkylation of phenols

Yoichiro Kuninobu, Masaki Yamamoto, Mitsumi Nishi, Tomoyuki Yamamoto, Takashi Matsuki, Masahito Murai, Kazuhiko Takai

Research output: Contribution to journalArticle

Abstract

A procedure yielding pure 2-(1-methylnonyl)phenol (1) as a colorless oil is presented. An oven-dried Schlenk flask with a Teflon-coated magnetic stir bar and a reflux condenser with a three-way stopcock is primarily used as paraphernalia. A discussion on ortho-monoalkylated phenol derivatives as important bioactive compounds and functional materials concludes the chapter.

Original languageEnglish
JournalOrganic Syntheses
Volume94
DOIs
Publication statusPublished - Jun 20 2018

Keywords

  • 2-(1-methylnonyl)phenol
  • Dirhenium decacarbonyl
  • Friedel-Crafts alkylation
  • Kugelrohr distillation
  • Monoalkylated phenols

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry

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  • Cite this

    Kuninobu, Y., Yamamoto, M., Nishi, M., Yamamoto, T., Matsuki, T., Murai, M., & Takai, K. (2018). Rhenium-catalyzed ortho-alkylation of phenols. Organic Syntheses, 94. https://doi.org/10.1002/0471264229.os094.20