Rhenium-catalyzed hydroamidation of unactivated terminal alkynes: Synthesis of (E)-enamides

S. Salprima Yudha; Yoichiro Kuninobu; Kazuhiko Takai

doi:10.1021/ol702564e

Rhenium-catalyzed hydroamidation of unactivated terminal alkynes: Synthesis of (E)-enamides

S. Salprima Yudha, Yoichiro Kuninobu, Kazuhiko Takai

Research output: Contribution to journal › Article › peer-review

50 Citations (Scopus)

Abstract

Reactions of cyclic amides with unactivated terminal alkynes in the presence of a catalytic amount of a rhenium complex provided (E)-enamides in high regio- and stereoselectivity (E:Z = >99:<1).

Original language	English
Pages (from-to)	5609-5611
Number of pages	3
Journal	Organic Letters
Volume	9
Issue number	26
DOIs	https://doi.org/10.1021/ol702564e
Publication status	Published - Dec 20 2007

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol702564e

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title = "Rhenium-catalyzed hydroamidation of unactivated terminal alkynes: Synthesis of (E)-enamides",

abstract = "Reactions of cyclic amides with unactivated terminal alkynes in the presence of a catalytic amount of a rhenium complex provided (E)-enamides in high regio- and stereoselectivity (E:Z = >99:<1).",

author = "{Salprima Yudha}, S. and Yoichiro Kuninobu and Kazuhiko Takai",

year = "2007",

month = dec,

day = "20",

doi = "10.1021/ol702564e",

language = "English",

volume = "9",

pages = "5609--5611",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "26",

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T1 - Rhenium-catalyzed hydroamidation of unactivated terminal alkynes

T2 - Synthesis of (E)-enamides

AU - Salprima Yudha, S.

AU - Kuninobu, Yoichiro

AU - Takai, Kazuhiko

PY - 2007/12/20

Y1 - 2007/12/20

N2 - Reactions of cyclic amides with unactivated terminal alkynes in the presence of a catalytic amount of a rhenium complex provided (E)-enamides in high regio- and stereoselectivity (E:Z = >99:<1).

AB - Reactions of cyclic amides with unactivated terminal alkynes in the presence of a catalytic amount of a rhenium complex provided (E)-enamides in high regio- and stereoselectivity (E:Z = >99:<1).

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U2 - 10.1021/ol702564e

DO - 10.1021/ol702564e

M3 - Article

C2 - 18031055

AN - SCOPUS:38349170142

VL - 9

SP - 5609

EP - 5611

JO - Organic Letters

JF - Organic Letters

SN - 1523-7060

IS - 26

ER -

Rhenium-catalyzed hydroamidation of unactivated terminal alkynes: Synthesis of (E)-enamides

Abstract

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