Rhenium-catalyzed allylation of C-H bonds of benzoic and acrylic acids

Yoichiro Kuninobu, Kazuhiro Ohta, Kazuhiko Takai

Research output: Contribution to journalArticle

37 Citations (Scopus)

Abstract

We have succeeded in the allylation of aromatic and olefinic C-H bonds of benzoic and acrylic acids using a rhenium catalyst, Re2(CO) 10. In this reaction, isomerization of the introduced allyl group to the 1-propenyl group did not occur.

Original languageEnglish
Pages (from-to)10791-10793
Number of pages3
JournalChemical Communications
Volume47
Issue number38
DOIs
Publication statusPublished - Oct 14 2011

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Allylation
Rhenium
Carbon Monoxide
Isomerization
Acrylics
Catalysts
Acids
acrylic acid

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Rhenium-catalyzed allylation of C-H bonds of benzoic and acrylic acids. / Kuninobu, Yoichiro; Ohta, Kazuhiro; Takai, Kazuhiko.

In: Chemical Communications, Vol. 47, No. 38, 14.10.2011, p. 10791-10793.

Research output: Contribution to journalArticle

Kuninobu, Yoichiro ; Ohta, Kazuhiro ; Takai, Kazuhiko. / Rhenium-catalyzed allylation of C-H bonds of benzoic and acrylic acids. In: Chemical Communications. 2011 ; Vol. 47, No. 38. pp. 10791-10793.
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