Rhenium-catalysed dehydrogenative borylation of primary and secondary C(sp3)-H bonds adjacent to a nitrogen atom

Masahito Murai, Tetsuya Omura, Yoichiro Kuninobu, Kazuhiko Takai

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Rhenium-catalysed C(sp3)-H bond borylation in the absence of any oxidant, hydrogen acceptor, or external ligand, with the generation of H2 as the sole byproduct is described. The transformation, which represents a rare example of rhenium-catalysed C(sp3)-H bond functionalisation, features high atom efficiency and simple reaction conditions. This journal is

Original languageEnglish
Pages (from-to)4583-4586
Number of pages4
JournalChemical Communications
Volume51
Issue number22
DOIs
Publication statusPublished - Mar 18 2015

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Rhenium
Nitrogen
Atoms
Oxidants
Byproducts
Hydrogen
Ligands

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Ceramics and Composites
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Materials Chemistry
  • Metals and Alloys

Cite this

Rhenium-catalysed dehydrogenative borylation of primary and secondary C(sp3)-H bonds adjacent to a nitrogen atom. / Murai, Masahito; Omura, Tetsuya; Kuninobu, Yoichiro; Takai, Kazuhiko.

In: Chemical Communications, Vol. 51, No. 22, 18.03.2015, p. 4583-4586.

Research output: Contribution to journalArticle

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