Rhenium- and manganese-catalyzed insertion of alkynes into a carbon-carbon single bond of cyclic and acyclic 1,3-dicarbonyl compounds

Yoichiro Kuninobu, Atsushi Kawata, Mitsumi Nishi, Salprima Yudha S, Jingjin Chen, Kazuhiko Takai

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

Treatment of alkynes with cyclic and acyclic 1,3-dicarbonyl compounds in the presence of a catalytic amount of a rhenium or manganese complex gives ring-expanded and carbon-chain extension products, respectively. In these reactions, alkynes insert into a non-strained carbon-carbon single bond of 1,3-dicarbonyl compounds. The ring-expansion reaction is also promoted by the addition of 4-Å molecular sieves instead of a catalytic amount of an isocyanide.

Original languageEnglish
Pages (from-to)1424-1433
Number of pages10
JournalChemistry - An Asian Journal
Volume4
Issue number9
DOIs
Publication statusPublished - Sep 1 2009

Keywords

  • Alkynes
  • C-c activation
  • Insertion
  • Manganese
  • Rhenium

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry

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