Rhenium- and manganese-catalyzed insertion of acetylenes into β-keto esters: Synthesis of 2-pyranones

Yoichiro Kuninobu, Atsushi Kawata, Mitsumi Nishi, Hisatsugu Takata, Kazuhiko Takai

Research output: Contribution to journalArticle

51 Citations (Scopus)

Abstract

Rhenium- and manganese-catalyzed reactions between β-keto esters and acetylenes, followed by treatment with tetrabutylammonium fluoride, gave 2-pyranone derivatives regioselectively.

Original languageEnglish
Pages (from-to)6360-6362
Number of pages3
JournalChemical Communications
Issue number47
DOIs
Publication statusPublished - 2008

Fingerprint

Rhenium
Alkynes
Acetylene
Manganese
Esters
Derivatives
tetrabutylammonium

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Rhenium- and manganese-catalyzed insertion of acetylenes into β-keto esters : Synthesis of 2-pyranones. / Kuninobu, Yoichiro; Kawata, Atsushi; Nishi, Mitsumi; Takata, Hisatsugu; Takai, Kazuhiko.

In: Chemical Communications, No. 47, 2008, p. 6360-6362.

Research output: Contribution to journalArticle

Kuninobu, Yoichiro ; Kawata, Atsushi ; Nishi, Mitsumi ; Takata, Hisatsugu ; Takai, Kazuhiko. / Rhenium- and manganese-catalyzed insertion of acetylenes into β-keto esters : Synthesis of 2-pyranones. In: Chemical Communications. 2008 ; No. 47. pp. 6360-6362.
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