RhCl(PPh3)3/NaI catalyst system for hydrosilylation of 1-alkynes: Stereodivergent syntheses of E-and Z-alkenylsilanes with heteroatom substituents on silicon

Atsunori Mori, Eisuke Takahisa, Hiroshi Kajiro, Kazunori Hirabayashi, Yasushi Nishihara, Tamejiro Hiyama

Research output: Contribution to journalArticle

60 Citations (Scopus)

Abstract

Both (E)-and (Z)-alkenylsilanes are synthesized by the reaction of hydrosilanes and 1-alkynes catalyzed by RhCl(PPh3)3/NaI or RhI(PPh3)3 highly selectively.

Original languageEnglish
Pages (from-to)443-444
Number of pages2
JournalChemistry Letters
Issue number5
DOIs
Publication statusPublished - 1998
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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