RhCl(PPh3)3/NaI catalyst system for hydrosilylation of 1-alkynes: Stereodivergent syntheses of E-and Z-alkenylsilanes with heteroatom substituents on silicon

Atsunori Mori, Eisuke Takahisa, Hiroshi Kajiro, Kazunori Hirabayashi, Yasushi Nishihara, Tamejiro Hiyama

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Abstract

Both (E)-and (Z)-alkenylsilanes are synthesized by the reaction of hydrosilanes and 1-alkynes catalyzed by RhCl(PPh3)3/NaI or RhI(PPh3)3 highly selectively.

Original languageEnglish
Pages (from-to)443-444
Number of pages2
JournalChemistry Letters
Issue number5
Publication statusPublished - 1998
Externally publishedYes

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Hydrosilylation
Alkynes
Silicon
Catalysts
chlorotris(triphenylphosphine)rhodium

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

RhCl(PPh3)3/NaI catalyst system for hydrosilylation of 1-alkynes : Stereodivergent syntheses of E-and Z-alkenylsilanes with heteroatom substituents on silicon. / Mori, Atsunori; Takahisa, Eisuke; Kajiro, Hiroshi; Hirabayashi, Kazunori; Nishihara, Yasushi; Hiyama, Tamejiro.

In: Chemistry Letters, No. 5, 1998, p. 443-444.

Research output: Contribution to journalArticle

Mori, Atsunori ; Takahisa, Eisuke ; Kajiro, Hiroshi ; Hirabayashi, Kazunori ; Nishihara, Yasushi ; Hiyama, Tamejiro. / RhCl(PPh3)3/NaI catalyst system for hydrosilylation of 1-alkynes : Stereodivergent syntheses of E-and Z-alkenylsilanes with heteroatom substituents on silicon. In: Chemistry Letters. 1998 ; No. 5. pp. 443-444.
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