@article{ca9f6189f04945c99171919b67369ab7,
title = "Rh-Catalyzed Dehydrogenative Cyclization Leading to Benzosilolothiophene Derivatives via Si-H/C-H Bond Cleavage",
abstract = "Straightforward syntheses leading to π-extended benzosilolothiophene (BST) derivatives by Rh-catalyzed dehydrogenative cyclization reactions have been developed. Electron-deficient ligands were effective for the reactions, and dppe-F20 gave the best result. This method could be applied to the synthesis of highly π-extended ladder-type BST derivatives, which exhibited fluorescence.",
author = "Koichi Mitsudo and Seiichi Tanaka and Ryota Isobuchi and Tomohiro Inada and Hiroki Mandai and Toshinobu Korenaga and Atsushi Wakamiya and Yasujiro Murata and Seiji Suga",
note = "Funding Information: This work was supported in part by a Grant-in-Aid for Scientific Research (C) (Nos. 25410042, 16K05695) from JSPS, Japan, by the Collaborative Research Program of Institute for Chemical Research, Kyoto University (Grant No. 2015-47), and by JST, ACT-C, Japan. Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",
year = "2017",
month = may,
day = "19",
doi = "10.1021/acs.orglett.7b00878",
language = "English",
volume = "19",
pages = "2564--2567",
journal = "Organic Letters",
issn = "1523-7060",
publisher = "American Chemical Society",
number = "10",
}