Abstract
Hydration structures of "nanosolutions" around both cation and anion for rubidium bromide confined in nanospaces (pore width = 1.1 nm) of activated carbon fiber were determined with EXAFS measurements and related analysis. The analytical results indicate that the ionic solutions confined in hydrophobic nanospaces tend to form an incomplete dehydration structure, because of the spatial restriction by the nanospace and capturing water molecules in the ordered structure.
| Original language | English |
|---|---|
| Pages (from-to) | 11860-11861 |
| Number of pages | 2 |
| Journal | Journal of the American Chemical Society |
| Volume | 124 |
| Issue number | 40 |
| DOIs | |
| Publication status | Published - Oct 9 2002 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Chemistry(all)
Cite this
Restricted hydration structures of Rb and Br ions confined in slit-shaped carbon nanospace. / Ohkubo, Takahiro; Konishi, Takehisa; Hattori, Yoshiyuki; Kanoh, Hirofumi; Fujikawa, Takashi; Kaneko, Katsumi.
In: Journal of the American Chemical Society, Vol. 124, No. 40, 09.10.2002, p. 11860-11861.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Restricted hydration structures of Rb and Br ions confined in slit-shaped carbon nanospace
AU - Ohkubo, Takahiro
AU - Konishi, Takehisa
AU - Hattori, Yoshiyuki
AU - Kanoh, Hirofumi
AU - Fujikawa, Takashi
AU - Kaneko, Katsumi
PY - 2002/10/9
Y1 - 2002/10/9
N2 - Hydration structures of "nanosolutions" around both cation and anion for rubidium bromide confined in nanospaces (pore width = 1.1 nm) of activated carbon fiber were determined with EXAFS measurements and related analysis. The analytical results indicate that the ionic solutions confined in hydrophobic nanospaces tend to form an incomplete dehydration structure, because of the spatial restriction by the nanospace and capturing water molecules in the ordered structure.
AB - Hydration structures of "nanosolutions" around both cation and anion for rubidium bromide confined in nanospaces (pore width = 1.1 nm) of activated carbon fiber were determined with EXAFS measurements and related analysis. The analytical results indicate that the ionic solutions confined in hydrophobic nanospaces tend to form an incomplete dehydration structure, because of the spatial restriction by the nanospace and capturing water molecules in the ordered structure.
UR - http://www.scopus.com/inward/record.url?scp=0037048660&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0037048660&partnerID=8YFLogxK
U2 - 10.1021/ja027144t
DO - 10.1021/ja027144t
M3 - Article
C2 - 12358524
AN - SCOPUS:0037048660
VL - 124
SP - 11860
EP - 11861
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 40
ER -