Regulation of fluoride ion release from Na2SiF6 contained in resin based on hydrophobic siloxane layer coating

S. Nakabo, Yasuhiro Torii, T. Itota, Masahiro Yoshiyama, K. Ishikawa, K. Suzuki

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Regulation of fluoride release from restorative resin or sealant is beneficial to patients as it will prevent the occurrence of the secondary caries. In this study, we evaluated whether or not the formation of a hydrophobic polysiloxane layer on the surface of the fluoride compound could contribute to the regulation of fluoride release from resin. First, sodium hexafluorosilicate (Na2SiF6) powder was treated with γ-methacryloxypropyltrimethoxysilane (γ-MPTS) and analysed with scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FT-IR) and electron spectroscopy for chemical analysis (ESCA). Analysis revealed that a hydrophobic polysiloxane layer was formed on the surface of Na2SiF6 powder. Heat treatment commonly used during γ-MPTS treatment was not necessary for the polysiloxane layer formation on the surface of Na2SiF6 powder. Then Na 2SiF6 powder treated with γ-MPTS was loaded in bis-GMA/TEG-DMA resin, immersed in distilled water and fluoride release was measured using a fluoride electrode. We found that the rate of fluoride release was significantly lower from the resin containing Na2SiF6 powder treated with γ-MPTS. We concluded, therefore, that γ-MPTS treatment and the resulting hydrophobic polysiloxane layer formation are very effective for the regulation of fluoride release from resin.

Original languageEnglish
Pages (from-to)675-681
Number of pages7
JournalJournal of Oral Rehabilitation
Volume29
Issue number7
DOIs
Publication statusPublished - Jul 2002

Fingerprint

Siloxanes
Fluorides
Ions
Powders
Bisphenol A-Glycidyl Methacrylate
Photoelectron Spectroscopy
Fourier Transform Infrared Spectroscopy
Electron Scanning Microscopy
Electrodes
Therapeutics
Hot Temperature
Water

Keywords

  • Fluoride release
  • Hydrophobic layer
  • Polysiloxane
  • Resin
  • Silane coupling agent
  • Sodium hexafluorosilicate

ASJC Scopus subject areas

  • Dentistry(all)
  • Medicine(all)

Cite this

Regulation of fluoride ion release from Na2SiF6 contained in resin based on hydrophobic siloxane layer coating. / Nakabo, S.; Torii, Yasuhiro; Itota, T.; Yoshiyama, Masahiro; Ishikawa, K.; Suzuki, K.

In: Journal of Oral Rehabilitation, Vol. 29, No. 7, 07.2002, p. 675-681.

Research output: Contribution to journalArticle

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