Abstract
This study investigated the regioselectivity of the intramolecular biaryl coupling reaction of the phenyl benzoate derivative which possesses a methyl or methoxy group at the meta-position of the phenoxy moiety. The type of base and the presence/absence of the phosphine ligand influenced the product ratio. A transition state model and the regioselectivity of the reaction are discussed.
| Original language | English |
|---|---|
| Pages (from-to) | 621-628 |
| Number of pages | 8 |
| Journal | Heterocycles |
| Volume | 88 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 2014 |
ASJC Scopus subject areas
- Analytical Chemistry
- Pharmacology
- Organic Chemistry
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Maeda, K., Matsukihira, T., Saga, S., Takeuchi, Y., Harayama, T., Horino, Y., & Abe, H. (2014). Regioselectivity of the intramolecular biaryl coupling reaction of 3-substituted phenyl 2-iodobenzoate using a palladium reagent. Heterocycles, 88(1), 621-628. https://doi.org/10.3987/COM-13-S(S)10