Regioselective Synthesis of Highly Substituted Furans via Tantalum-Alkyne Complexes

Kazuhiko Takai, Makoto Tezuka, Yasutaka Kataoka, Kiitiro Utimoto

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

: A variety of 2,3,4-trisubstituted furans are prepared by treatment of tantalum—alkyne complexes with aldehydes, followed by addition of an isocyanide in DMR-PhH-THF (1:1:1). Transition metals exhibit a variety of interesting reactivities, thereby suggesting new methods in organic synthesis. We disclose here a regioselective preparation of highly substituted furans1from three components, i.e.

Original languageEnglish
Pages (from-to)5310-5312
Number of pages3
JournalJournal of Organic Chemistry
Volume55
Issue number19
DOIs
Publication statusPublished - Jan 1 1990
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry

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